109720-12-9

Upstream product

• 75-15-0 carbon disulfide 
• 124-40-3 dimethyl amine 
• 99-09-2 3-nitro-aniline 
• 586-36-7 3-nitrophenyldiazonium tetrafluoroborate 
• 6293-62-5 bis-(3-nitro-phenyl)-iodonium ; chloride 
• 128-04-1 sodium dimethyldithiocarbamate 

Downstream Products

• 37692-06-1 (4-methoxyphenyl)(3-nitrophenyl)sulfide 
• 625105-45-5 4-chlorophenyl 3′-nitrophenyl sulfide 

Relevant academic research and scientific papers

Aryldithiocarbamates as thiol alternatives in Cu-catalyzed C(aryl)-S coupling reactions using aryldiazonium tetrafluoroborate salts

An efficient method for the synthesis of unsymmetrical diaryl sulfides has been developed by the C-S cross coupling of aryldithiocarbamates and aryldiazonium salts in the presence of CuI-2,2′-bipyridine and Zn. Aryldithiocarbamate compounds have been used here as thiol substitutes. The protocol shows wide substrate scope and good yields of the products.

Transition-Metal-Free C-S Bond Formation: Aqueous Synthesis of S-Aryl Dithiocarbamates by the use of Stable Arenediazonium Salts Mediated by Nano-Magnetic Supported Silica Sulfonic Acid

A convenient and transition-metal-free method for the synthesis of S-aryl dithiocarbamates based on the reaction of stable arenediazonium nano-magneto silica sulfates (ArN2+-OSO3-SiO2@Fe3O4) with dithiocarbamic acid at room temperature was studied. Avoiding the use of any hazardous transition metal, simple procedure, low cast, and short reaction time are noteworthy advantages of this methodology.