109730-22-5Relevant articles and documents
Hydrophosphinylation of unactivated terminal alkenes catalyzed by nickel chloride
Ortial, Stephanie,Fisher, Henry C.,Montchamp, Jean-Luc
, p. 6599 - 6608 (2013/07/26)
The room-temperature hydrophosphinylation of unactivated monosubstituted alkenes using phosphinates (ROP(O)H2) and catalytic NiCl2 in the presence of dppe is described. The method is competitive with prior palladium-catalyzed reactio
Palladium-catalyzed cross-coupling of H-phosphinate esters with chloroarenes
Deal, Eric L.,Petit, Christelle,Montchamp, Jean-Luc
supporting information; experimental part, p. 3270 - 3273 (2011/08/03)
The palladium-catalyzed cross-coupling reaction between H-phosphinate esters and chloroarenes or chloroheteroarenes is described. This reaction is the first general metal-catalyzed phosphorus-carbon bond-forming reaction between a phosphorus nucleophile and chloroarenes.