109870-10-2

Basic information

• Product Name: Pyridine, 1,2,3,6-tetrahydro-1-(phenylmethyl)-4-[(trimethylsilyl)oxy]-
• CAS NO: 109870-10-2
• Molecular Formula: C15H23NOSi
• Molecular Weight: 261.439
• Mol File: 109870-10-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pyridine, 1,2,3,6-tetrahydro-1-(phenylmethyl)-4-[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 1,2,3,6-tetrahydro-1-(phenylmethyl)-4-[(trimethylsilyl)oxy]-(109870-10-2)
• EPA Substance Registry System: Pyridine, 1,2,3,6-tetrahydro-1-(phenylmethyl)-4-[(trimethylsilyl)oxy]-(109870-10-2)

Safety Data

• Hazardous Substances Data: 109870-10-2(Hazardous Substances Data)

Upstream product

• 3612-20-2 1-phenylmethyl-4-piperidone 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 1026046-87-6 [(S)-3-(1-Benzyl-4-oxo-piperidin-3-yl)-1-(2-tert-butoxycarbonylamino-ethylcarbamoyl)-3-oxo-propyl]-carbamic acid benzyl ester 
• 1026594-26-2 (S)-4-(1-Benzyl-4-oxo-piperidin-3-yl)-2-benzyloxycarbonylamino-4-oxo-butyric acid 
• 104860-16-4 1-benzyl-3-bromopiperidine-4-one 
• 919491-13-7 (E)-(1''S,3a''R,7a''S)-tert-butyl 3-[1'-benzyl-4'-(1''-tert-butoxy-7a''-methyl-2'',3'',3a'',6'',7'',7a''-hexahydro-1''H-indene-5''-yl)-1',2',5',6'-tetrahydropyridine-3'-yl]acrylate 
• 919491-10-4 1-benzyl-5-bromo-4-(1-tert-butoxy-7a-methyl-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yl)-1,2,3,6-tetrahydro-pyridine 
• 919491-07-9 1-benzyl 5-bromo-4-trifluromethanesulfonyloxy-1,2,3,6-tetrahydropyridine 

Relevant articles and documents

A Solvent-Free Reaction for Silyl Enol Ethers Synthesis

Silyl enol ethers are extremely useful nucleophilic intermediates for chemical transformations because they are synthetically versatile substrates for a wide range of C-C bond-forming reactions. Here, we present a new, mild, and solvent-free procedure for the synthesis of silyl enol ethers that employs a catalytic amount of solid-supported base and an equimolar amount of N, O -(bistrimethylsilyl)acetamide as a silylating agent.