109972-84-1Relevant academic research and scientific papers
Towards a Molecular Abacus
Reddington, Mark V.,Slawin, Alexandra M. Z.,Spencer, Neil,Stoddart, J. Fraser,Vicent, Cristina,Williams, David J.
, p. 630 - 634 (1991)
The solid state and solution structures of the 1:1 complex formed between the cyclobis(paraquat-p-phenylene) tetracationic cyclophane and 1,5-dimethoxynaphthalene has led to the successful design and characterisation by X-ray crystallography of a prototyp
De novo asymmetric synthesis of (?)-nanaomycin A
Zhang, Qi,O'Doherty, George A.
, p. 4994 - 4999 (2018)
The de novo asymmetric total synthesis of (?)-nanaomycin A is described. The entirely linear route required only 13 steps from commercially available starting materials (3% overall yield). Key transformations include a Claisen rearrangement, an asymmetric
Anion induced displacement studies in naphthalene diimide containing interpenetrated and interlocked structures
Mullen, Kathleen M.,Davis, Jason J.,Beer, Paul D.
scheme or table, p. 769 - 776 (2009/06/20)
This article describes investigations into the development of supramolecular systems capable of sensing anions through either displacement type assays or molecular motion. An electron deficient naphthalene diimide thread and an electron rich isophthalamid
Synthesis of some substituted naphthalenes as potential intermediates for polyethers and terpenoids
Banerjee,Poon,Laya,Azocar
, p. 1815 - 1820 (2007/10/03)
1-Benzyloxy-5-hydroxynaphthalene and 1,6-dimethyl-5-hydroxynaphthalene were prepared from 5-methoxy-α-tetralone. 6-Methoxy-α-tetralone was converted to 1,6-dimethoxy-2-isopropylnaphthalene.
Synthetic studies on kinamycin antibiotics: Synthesis of a trioxygenated benz[f]indenone and its Diels-Alder reaction to a kinamycin skeleton
Kitani, Yasuo,Morita, Akiko,Kumamoto, Takuya,Ishikawa, Tsutomu
, p. 1186 - 1195 (2007/10/03)
A benzo[b]fluorene skeleton such as 10, a basic four-ring system in the revised diazo structures 3 of kinamycin antibiotics, was synthesized by Diels-Alder reaction between dienophile 4,7,8-trioxygenated 1H-benz[f]inden-1-one 11 and Danishefsky-type diene 7. The indenone 11 was prepared by deoxygenation of 2,3-dihydro-1H-benz[f]inden-1-one 12 with the inexpensive 1 -hydroxy-1.2-benziodoxol-3(1H)-one 1-oxide (IBX) after modification of the known protocol. Indenone 12 in turn was obtained from naphthalene-1,5-diol (14) via an intramolecular Friedel-Crafts cyclization of naphthalene-2-propanoic acid 13 as a key step.
A simple and efficient method for the preparation of 1-benzyloxy-5- hydroxynaphthalene
Becher, Jan,Matthews, Owen A.,Nielsen, Mogens B.,Raymo, Fran?isco M.,Stoddart, J. Fraser
, p. 330 - 332 (2007/10/03)
1,5-Dihydroxynaphthalene is a versatile π-electron rich aromatic ring system which has been employed widely for the construction of mechanically- interlocked molecular compounds and supramolecular complexes. A much-needed procedure for its transformation into 1-benzyloxy-5-hydroxynaphthalene has been developed. It involves (i) bisacetylation of 1,5-dihydroxynaphthalene, (ii) reductive removal of one of the two acetyl groups, (iii) benzylation, and (iv) cleavage of the remaining acetyl group.
Synthesis, structure and photophysics of neutral π-associated [2]catenanes
Hamilton, Darren G.,Davies, John E.,Prodi, Luca,Sanders, Jeremy K. M.
, p. 608 - 620 (2007/10/03)
The supramolecular utility of a neutral π-stacking system of aromatic donors and acceptors is illustrated with the syntheses of three neutral [2]catenanes. These templated syntheses are based on the oxidative dimerisation of electron-deficient aromatic di
A Self-organised Layered Superstructure of Arrayed Pseudorotaxanes
Ashton, Peter R.,Philp, Douglas,Spencer, Neil,Stoddart, J. Fraser,Williams, David. J
, p. 181 - 184 (2007/10/02)
A pseudorotaxane, built up from a macrocyclic cyclophane containing two aromatic ?-acceptors and an acyclic molecule containing three aromatic ?-donors, has the ability to undergo self-organization on crystallistion to form a layered superstructure of
