111080-27-4

Basic information

• Product Name: (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol
• CAS NO: 111080-27-4
• Molecular Weight: 126.155
• Mol File: 111080-27-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol(111080-27-4)
• EPA Substance Registry System: (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol(111080-27-4)

Safety Data

• Hazardous Substances Data: 111080-27-4(Hazardous Substances Data)

Upstream product

• 59274-95-2 7-oxa-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde 
• 110-00-9 furan 
• 107-02-8 acrolein 
• 88517-51-5 7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid methyl ester 
• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid 
• 17791-32-1 exo-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester 
• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid 

Downstream Products

• 132929-34-1 [(1RS,2RS,4RS)-7-oxabicyclo[2.2.1]hept-5-en-2-yl]methyl benzoate 
• 132929-37-4 2-exo-phenylselenyl-4.8-dioxatricyclo<4.2.1.0.^3.7>nonane 
• 132929-38-5 2-exo-phenylsulfenyl-4.8-dioxatricyclo<4.2.1.0.^3.7>nonane 
• 140901-69-5 (+/-)-3-exo-Acetoxy-5-endo-acetoxymethyl-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-73-1 (+/-)-2-exo-Acetoxy-5-endo-acetoxymethyl-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 141041-60-3 DL-(1,2,3,4/5)-3-Acetamido-5-acetoxymethyl-1,2,4-tri-O-acetyl-1,2,4-cyclohexanetriol 
• 140901-68-4 (+/-)-5-endo-Acetoxymethyl-3-exo-hydroxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-72-0 (+/-)-5-endo-Acetoxymethyl-2-exo-hydroxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-74-2 (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-70-8 (+/-)-5-endo-Acetoxymethyl-3-exo-methylsulfonyloxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-77-5 (+/-)-5-endo-Hydroxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-78-6 DL-(1,2,3/4,6)-3-Acetamido-6-acetoxymethyl-1,2-di-O-acetyl-4-bromo-1,2-cyclohexanediol 
• 140901-83-3 DL-(1,2,3,4/5)-3-Acetamido-1,2,4-tri-O-acetyl-5-bromomethyl-1,2,4-cyclohexanetriol 
• 140901-81-1 DL-(1,2,3/4,6)-2-Acetamido-1,3-di-O-acetyl-4-bromo-6-bromomethyl-1,3-cyclohexanediol 

Relevant articles and documents

Polypropionates from 7-oxanorbornene derivatives. A stereoselective and divergent synthesis of fragments with four contiguous chiral centers

The epimeric stereotetrads 12 and 14 have been prepared starting from the Diels-Alder endo adduct of furan and acrylic acid. The key steps of the route were the alkylative cleavage of the oxygen bridge and the transformation of the resulting cyclic vinyl

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Synthesis of novel carbocyclic nucleoside analogues derived from 7-oxabicyclo[2.2.1]heptane-2-methanol

Hydroboration of [(lR*,2R*,4R*)-7-oxabicyclo[2.2.1]hept- 5-en-2-yl]methyl benzoate (5), which was prepared by Diels-Alder reaction of furan with acrolein and subsequent reduction and benzoylation of the Diels-Alder product, afforded [(lR*,2S*,4S*,6S*)-6-h