111400-69-2

Basic information

• Product Name: ethyl 4-methyl-2,5-diphenyl-1H-pyrrole-3-carboxylate
• Synonyms: ethyl 4-methyl-2,5-diphenyl-1H-pyrrole-3-carboxylate
• CAS NO: 111400-69-2
• Molecular Weight: 305.376
• Mol File: 111400-69-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl 4-methyl-2,5-diphenyl-1H-pyrrole-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-methyl-2,5-diphenyl-1H-pyrrole-3-carboxylate(111400-69-2)
• EPA Substance Registry System: ethyl 4-methyl-2,5-diphenyl-1H-pyrrole-3-carboxylate(111400-69-2)

Safety Data

• Hazardous Substances Data: 111400-69-2(Hazardous Substances Data)

Upstream product

• 70-11-1 α-bromoacetophenone 
• 53256-19-2 ethyl (Z)-3-amino-3-phenylacrylate 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 29113-48-2 ethyl 2-benzoyl-4-oxo-4-phenylbutanoate 
• 111400-50-1 ethyl 2-benzoyl-2-methyl-4-oxo-4-phenylbutanoate 
• 111400-62-5 3-Methyl-2,5-diphenyl-3H-pyrrole-3-carboxylic acid ethyl ester 

Relevant articles and documents

Visible-Light-Induced C (sp3)-H Functionalization of Tosylhydrazones: Synthesis of Polysubstituted Pyrroles under Metal-Free Conditions

Iodine catalyzed C (sp3)-H functionalization of tosylhydrazones with β-enamino esters under visible light irradiation for the synthesis of trisubstituted pyrroles has been described. The present method is also applicable to α- substituted tosyl

THERMAL REARRANGEMENT OF 3H-PYRROLES BY COMPETITIVE -SIGMATROPIC SHIFTS, AND THE REVERSIBILITY OF THE 3H- TO 2H-PYRROLE INTERCONVERSION

3-Ethoxycarbonyl-3H-pyrroles are converted via thermal -ester shifts to the isomeric 1H-pyrrole-4- and N-esters.Isolable intermediate 2H-pyrroles are converted into the same products, and also into the 3H-pyroles, demonstrating conclusively the reversibility of the 3H- to 2H-pyrrole interconversion.