111678-75-2Relevant academic research and scientific papers
Reaction of perfluoroalkyl iodides with 2-substituted 5-nitro-1,3-dioxane lithium salts
Galeeva,Zorin,Makaeva,Trifonova,Rakhmankulov
, p. 782 - 785 (2007/10/03)
Perfluoroalkyl iodides (C4F9I, C6F13I, C8F17I) react with 2-substituted 5-nitro-1,3-dioxane lithium salts in DMSO (24 h, 20°C) under argon, yielding 56-75% of 2-substituted 5-nitro-5-perfluoroalkyl-1,3-dioxanes. UV irradiation accelerates the reaction.
SUBSTITUTION OF THE CHLORINE ATOM IN 2,4-DINITROCHLOROBENZENE BY THE 2-R-5-NITRO-1,3-DIOXANYL RESIDUE
Kirillov, I. T.,Kukovitskii, D. M.,Zorin, V. V.,Kasatkina, A. A.,Rakhmankulov, D. L.
, p. 529 - 531 (2007/10/02)
The reaction of the lithium salts of 5-nitro-2-R-1,3-dioxanes with 2,4-dinitrochlorobenzene leads to the formation of 2-R-5-nitro-5-(2,4-dinitrophenyl)-1,3-dioxanes with the axial-equatorial arrangement of the nitro and 2,4-dinitrophenyl substituents.
