111717-08-9

Basic information

• Product Name: t-butyl 2-(t-butoxycarbonylamino)-4-oxo-4-phenylbutanoate
• CAS NO: 111717-08-9
• Molecular Weight: 349.427
• Mol File: 111717-08-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: t-butyl 2-(t-butoxycarbonylamino)-4-oxo-4-phenylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl 2-(t-butoxycarbonylamino)-4-oxo-4-phenylbutanoate(111717-08-9)
• EPA Substance Registry System: t-butyl 2-(t-butoxycarbonylamino)-4-oxo-4-phenylbutanoate(111717-08-9)

Safety Data

• Hazardous Substances Data: 111717-08-9(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 117833-60-0 N-tert-butoxycarbonyl-α-bromoglycine tert-butyl ester 
• 111652-20-1 N-(tert-butoxycarbonyl)glycine tert-butyl ester 
• 27532-96-3 glycine tert-butyl ester hydrochloride 
• 24424-99-5 di-tert-butyl dicarbonate 
• 111652-21-2 t-Butyl N-(butoxycarbonyl)iminoacetate 
• 7196-01-2 4-(1-phenylvinyl)morpholine 
• 13735-81-4 1-styrenyloxytrimethylsilane 

Downstream Products

• 54631-37-7 2-amino-4-oxo-4-phenyl-butyric acid ; hydrochloride 
• 15121-92-3 α-amino-γ-oxo-(+/-)-benzenebutanoic acid 

Relevant articles and documents

NEW SYNTHESES OF α-AMINO ACIDS BASED ON N-ACYLIMINO ACETATES

The reaction of N-acylamino-2-bromoacetates 2 ( via N-acylimino acetates 3 ) with higher order mixed cuprates, trimethylsilyl enol ethers and β-dicarbonyl compounds leads to a variety of α-amino acid derivatives.Their conversion into the free amino acids can be conveniently carried out by the use of t-butyl protection.In case of the N-acetyl compounds cleavage of the protecting group and optical resolution can be achieved in one step hog renal acylase.