112137-63-0

Basic information

• Product Name: 2-Deoxy-3,5-di-O-benzoylribofuranose
• Synonyms: 2-Deoxy-3,5-di-O-benzoylribofuranose;2-Deoxy-D-ribofuranose 3,5-Dibenzoate
• CAS NO: 112137-63-0
• Molecular Formula: C₁₉H₁₈O₆
• Molecular Weight: 342.34262
• Product Categories: Aromatics;Carbohydrates & Derivatives;Intermediates;Aromatics, Carbohydrates & Derivatives, Intermediates
• Mol File: 112137-63-0.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
• Stability: Hygroscopic
• CAS DataBase Reference: 2-Deoxy-3,5-di-O-benzoylribofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Deoxy-3,5-di-O-benzoylribofuranose(112137-63-0)
• EPA Substance Registry System: 2-Deoxy-3,5-di-O-benzoylribofuranose(112137-63-0)

Safety Data

• Hazardous Substances Data: 112137-63-0(Hazardous Substances Data)

Usage

Uses

2-Deoxy-3,5-di-O-benzoylribofuranose (cas# 112137-63-0) is a compound useful in organic synthesis.

Upstream product

• 98-88-4 benzoyl chloride 
• 51255-17-5 (2S,3R)-2-Hydroxymethyl-5-methoxy-tetrahydro-furan-3-ol 
• 108647-88-7 ((2R,3S)-3-(benzoyloxy)-5-methoxytetrahydrofuran-2-yl)methyl benzoate 
• 51255-17-5 1-O-methyl-2-deoxy-D-ribofuranoside 
• 452-51-7 D-2-deoxyribose 
• 533-67-5 2-deoxy-D-ribose 
• 51785-70-7 methyl 3,5-dibenzoyloxy-2-deoxy-β-D-erythropentofuranoside 
• 80339-59-9 methyl 3,5-dibenzoyloxy-2-deoxy-α-D-erythropentofuranoside 

Downstream Products

• 145417-01-2 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside 
• 51255-12-0 1-O-acetyl-3,5-di-O-benzoyl-2-deoxy-D-erythro-pentafuranose 
• 140186-59-0 methyl 2,3-di-O-benzyl-6-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-glucopyranoside 
• 140186-57-8 1,2:3,4-di-O-isopropylidene-5-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-galactopyranoside 
• 140186-58-9 1,2:5,6-di-O-isopropylidene-3-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-glucofuranoside 
• 140186-56-7 methyl 2,3-O-isopropylidene-5-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-ribofuranoside 
• 55734-51-5 1,4-anhydro-2-deoxy-3,5-di-O-benzoyl-D-erythro-pent-1-enitol 
• 870181-69-4 (2R,3S,5R)-5-(3-Benzooxazol-2-yl-2-hydroxy-phenyl)-2-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-tetrahydro-furan-3-ol 
• 870181-65-0 C₃₂H₂₅NO₇ 
• 870181-67-2 (2R,3S,5R)-5-(3-Benzooxazol-2-yl-2-hydroxy-phenyl)-2-hydroxymethyl-tetrahydro-furan-3-ol 
• 870181-62-7 C₁₉H₁₇FO₅ 
• 80311-45-1 C₂₃H₂₄O₇ 
• 80311-45-1 C₂₃H₂₄O₇ 
• 35898-30-7 C₂₄H₂₂N₂O₇ 

Relevant articles and documents

Iron-Catalyzed Radical Cleavage/C?C Bond Formation of Acetal-Derived Alkylsilyl Peroxides

A novel radical-based approach for the iron-catalyzed selective cleavage of acetal-derived alkylsilyl peroxides, followed by the formation of a carbon–carbon bond is reported. The reaction proceeds under mild reaction conditions and exhibits a broad substrate scope with respect to the acetal moiety and the carbon electrophile. Mechanistic studies suggest that the present reaction proceeds through a free-radical process involving carbon radicals generated by the homolytic cleavage of a carbon–carbon bond within the acetal moiety. A synthetic application of this method to sugar-derived alkylsilyl peroxides is also described.

Differential solvation and tautomer stability of a model base pair within the minor and major grooves of DNA

2-(2′-Hydroxyphenyl)benzoxazole (HBO) may be used as a model base pair to study solvation, duplex environment, and tautomerization within the major and minor groves of DNA duplexes. In its ground state, HBO possesses an enol moiety which may be oriented s

Stereoselective synthesis of α-linked 2-deoxysaccharides and furanosaccharides by the use of 2-deoxy 2-pyridyl-1-thio pyrano- and furanosides as donors and methyl iodide as an activator

A practical and highly stereoselective glycosidation methodology is described, where anomeric mixture of 2-deoxy 2-pyridyl-1-thiopyranoside donors (1-3,27) have been coupled with several sugar alcohols (4-8,29,31) on activation by methyl iodide to obtain axially linked 2-deoxysaccharides (9-17,30,32,33). Application of this method for the synthesis of disaccharide fragment 28 of avermectin is also described. Utility of this method is also shown by use of 2-pyridyl-1-thiofuranosides (34-36) as donors to prepare α-linked furanosides (42-51).