112529-01-8Relevant articles and documents
DDQ-mediated Direct C(sp3)-H Cyanation of Benzyl Ethers and 1,3-Diarylpropenes under Solvent- and Metal-free Conditions
Kong, Shanshan,Zhang, Lingqiong,Dai, Xiaoli,Tao, Lianzhi,Xie, Chunsong,Shi, Lei,Wang, Min
, p. 2453 - 2456 (2015)
A direct cyanation of benzyl ethers and 1,3-diarylpropenes with TMSCN was performed under solvent- and metal-free conditions. This oxidative cross dehydrative coupling (CDC) reaction was promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and provided rapid access to a broad range of nitriles in good to excellent yields.
Efficient assembly of α-aryl and α-vinyl nitriles via iron-catalyzed ether bond activation
Fan, Xiaohui,Guo, Kun,Guan, Yong-Hong,Fu, Lin-An,Cui, Xiao-Meng,Lv, Hao,Zhu, Hong-Bo
, p. 1068 - 1071 (2014/02/14)
A novel and practical method for the synthesis of diverse α-aryl and α-vinyl nitriles was developed via an iron-catalyzed sp3 C-O ether bond cleavage with C-C bond formation in the reaction of π-activated ethers with TMSCN.
A Facile Synthesis of 1,5-Dienes and β,γ-Unsaturated Nitriles via Trityl Perchlorate-Catalyzed Allylation
Murakami, Masahiro,Kato, Takashi,Mukaiyama, Teruaki
, p. 1167 - 1170 (2007/10/02)
In the presence of a catalytic amount of trityl perchlorate, secondary and tertiary allyl ethers smoothly react with allylsilanes and silyl cyanide to give the corresponding 1,5-dienes and β,γ-unsaturated nitriles, respectively, in good yields.
