112970-72-6Relevant academic research and scientific papers
AN INTERESTING CHEMOSELECTIVITY IN PALLADATION OF AROMATIC BROMIDES
Yokoyama, Yuusaku,Takashima, Mitsuru,Higaki, Chitose,Shidori, Kazuko,Moriguchi,Shoko,et al.
, p. 1739 - 1742 (2007/10/02)
The reaction of various aromatic bromides with ethyl acrylate in the presence of stoichiometric amount of Pd(OAc)2 gave the vinylated products without affecting the carbon-bromine bond.
Palladium-Catalyzed Coupling of 2-Bromoanilines with Vinylstannanes. A Regiocontrolled Synthesis of Substituted Indoles
Krolski, Michael E.,Renaldo, Alfred F.,Rudisill, Duane E.,Stille, J. K.
, p. 1170 - 1176 (2007/10/02)
The palladium-catalyzed cross-coupling reaction of aryl halides and triflates with vinylstannane reagents has been used to produce a variety of substituted indoles.The mild reaction conditions and selectivity inherent in the coupling reaction have been utilized to produce regiochemically pure 4-, 5-, and 6-substituted indoles.
