114996-66-6

Basic information

• Product Name: 1-phenylsulfonylindoline-3-methanol
• Synonyms: 1-phenylsulfonylindoline-3-methanol
• CAS NO: 114996-66-6
• Molecular Weight: 289.355
• Mol File: 114996-66-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenylsulfonylindoline-3-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylsulfonylindoline-3-methanol(114996-66-6)
• EPA Substance Registry System: 1-phenylsulfonylindoline-3-methanol(114996-66-6)

Safety Data

• Hazardous Substances Data: 114996-66-6(Hazardous Substances Data)

Upstream product

• 181281-13-0 N-(2-Iodo-phenyl)-N-oxiranylmethyl-benzenesulfonamide 
• 114996-61-1 N-(2-Bromo-phenyl)-N-prop-2-ynyl-benzenesulfonamide 
• 114996-65-5 1-(phenylsulfonyl)-3-vinylindoline 
• 21226-31-3 N-(2-bromophenyl)-S-phenylsulfonamide 
• 98-09-9 benzenesulfonyl chloride 
• 54189-90-1 N-(2-iodophenyl)benzenesulfonamide 
• 615-43-0 2-iodophenylamine 
• 114996-67-7 1-Benzenesulfonyl-2,3-dihydro-1H-indole-3-carbaldehyde 
• 114996-64-4 3-methylidene-1-(phenylsulfonyl)indoline 
• 917-54-4 methyllithium 

Downstream Products

• 130469-60-2 1-(tert-Butyloxycarbonyl)-3-(methanesulfonyloxymethyl)indoline 

Relevant articles and documents

Development of highly chemoselective bulky zincate complex, tBu 4ZnLi2: Design, structure, and practical applications in small-/macromolecular synthesis

We present full details of the unique reactivities of the newly developed dianion-type bulky zincate, dilithium tetra-ferf-butylzincate (tBu 4ZnLi2). With this reagent, halogen-zinc exchange reaction of variously functionalized haloaromatics and anionic polymerization of N-isopropylacrylamide (NIPAm)/styrene with excellent chemoselectivity were realized. Halogen-zinc exchange reaction followed by electrophilic trapping with propargyl bromide provided a convenient route to functionalized phenylallenes, particularly those with electrophilic functional groups (such as cyano, amide and halogens). Spectral and computational studies of the structure in the gas and liquid phases indicated extraordinary stabilization of this dianion-type zincate by its bulky ligands.

Unique reactivities of new highly coordinated ate complexes of organozinc derivatives

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