115-89-9

Basic information

• Product Name: DIPHENYL METHYL PHOSPHATE
• Synonyms: phosphoricaciddiphenylmethylester;DIPHENYL METHYL PHOSPHATE, TECH., 80%;METHYL DIPHENYL PHOSPHATE;DIPHENYL METHYL PHOSPHATE;methylphenylphosphate;Phosphoric acid, methyl diphenyl ester;phosphoricacid,methyldiphenylester
• CAS NO: 115-89-9
• Molecular Formula: C₁₃H₁₃O₄P
• Molecular Weight: 264.21
• Mol File: 115-89-9.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 125 °C/0.03 mmHg(lit.)
• Flash Point: 113 °C
• Appearance: /
• Density: 1.23 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.000532mmHg at 25°C
• Refractive Index: n20/D 1.537(lit.)
• Water Solubility: 2g/L(25 oC)
• CAS DataBase Reference: DIPHENYL METHYL PHOSPHATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIPHENYL METHYL PHOSPHATE(115-89-9)
• EPA Substance Registry System: DIPHENYL METHYL PHOSPHATE(115-89-9)

Safety Data

• Hazardous Substances Data: 115-89-9(Hazardous Substances Data)

Usage

Chemical Properties

Clear, oily liquid. Non-flammable.

Uses

Different sources of media describe the Uses of 115-89-9 differently. You can refer to the following data:
1. Diphenyl Methyl Phosphate is a phosphorus flame retardant additive.
2. Ignition control compound.

InChI:InChI=1/C13H13O4P/c1-15-18(14,16-12-8-4-2-5-9-12)17-13-10-6-3-7-11-13/h2-11H,1H3

Upstream product

• 186581-53-3 diazomethane 
• 838-85-7 diphenyl hydrogen phosphate 
• 2533-69-9 methyl 2,2,2-trichloroacetimidate 
• 84812-10-2 diphenyl methyl phosphite ozonide 
• 67-56-1 methanol 
• 108-95-2 phenol 
• 26386-88-9 diphenyl phosphoryl azide 
• 10359-36-1 4-nitro-phenyl diphenyl phosphate 
• 3577-87-5 diphenyl methyl phosphite 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 677-24-7 methyl dichlorophosphoridate 
• 139-02-6 sodium phenoxide 
• 78605-38-6 Diphenyl 2-oxo-3-oxazolinylphosphonate 
• 29833-83-8 triphenyl phosphite ozonide 

Downstream Products

• 838-85-7 diphenyl hydrogen phosphate 
• 1005-64-7 trans-1-phenyl-1-butene 
• 934-10-1 3-phenylbut-1-ene 
• 25723-74-4 diphenyl(trimethylsilyl)phosphate 
• 6921-14-8 Diphenyl potassium phosphate 
• 74-88-4 methyl iodide 
• 1075702-09-8 methyl bis(2-hydroxyphenyl)phosphinate 
• 81041-84-1 diphenyl(α-naphthylphenylmethylsilyl)phosphate 
• 3279-55-8 sodium diphenyl phosphate 

Relevant articles and documents

Efficient and convenient one-pot synthesis of phosphoramidates and phosphates

A simple and efficient one-pot method is described for the synthesis of phosphoramidates/phosphates in excellent yields from dialkylphosphites and trichloroisocyanuric acid in acetonitrile and subsequent treatment with dialkyl amines/alcohols. The procedure is operationally simple, has reduced reaction times, and uses a one-pot procedure. Copyright Taylor & Francis Group, LLC.

Recyclable copper catalyst on chitosan for facile preparation of alkyl/aryl mixed phosphates via deaminated esterification between diphenylphosphoryl azides and aliphatic alcohols

An efficient methodology was established for the preparation of alkyl/aryl mixed phosphates under aerobic conditions promoted by a easily recoverable heterogeneous catalyst. This highly active copper catalyst was obtained by directly mixing of copper precursor with chitosan solution, followed by a simple work-up process. In this catalytic system, different phosphoryl azides and aliphatic alcohols were employed to generate desired products in moderate to excellent yields with good functional group tolerance. This protocol provided a practical application of the chitosan supported heterogeneous copper catalyst towards a novel P–O bond formation.

Copper catalyzed synthesis of aryl/alkyl mixed phosphates from diphenylphosphoryl azides and aliphatic alcohols under mild conditions

An efficient and convenient one-pot protocol is developed to prepare aryl/alkyl mixed phosphates in the presence of copper catalyst under exceptionally mild conditions. A series of versatile, ubiquitous, and inexpensive phosphoryl azides and aliphatic alcohols are combined for the first time ever. Diphenylphosphoryl azide is employed as novel phosphors reagent through an unexpected cleavage of P[sbnd]N bond. The transformation is advantageous with respect to a broad of functional group compatibility and different esterification products are isolated in good to excellent results. This new catalytic system represents a superior platform towards a mild, operationally simple, practical, and scalability alternative to access target molecules. Furthermore, a plausible mechanism is proposed based on insightful mechanistic studies.