1152-75-6

Basic information

• Product Name: Methanimidamide, N,N'-bis(4-methoxyphenyl)-
• CAS NO: 1152-75-6
• Molecular Formula: C15H16N2O2
• Molecular Weight: 256.304
• Mol File: 1152-75-6.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: Methanimidamide, N,N'-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanimidamide, N,N'-bis(4-methoxyphenyl)-(1152-75-6)
• EPA Substance Registry System: Methanimidamide, N,N'-bis(4-methoxyphenyl)-(1152-75-6)

Safety Data

• Hazardous Substances Data: 1152-75-6(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 122-51-0 orthoformic acid triethyl ester 
• 5470-34-8 4-methoxyformanilide 
• 77-78-1 dimethyl sulfate 
• 10076-13-8 N,N'-bis(4-methoxyphenyl)carbodiimide 
• 68-12-2 N,N-dimethyl-formamide 
• 100-00-5 4-chlorobenzonitrile 
• 99-99-0 1-methyl-4-nitrobenzene 
• 2293-07-4 1-(4-methoxyphenyl)thiourea 
• 2293-07-4 (4-methoxy-phenyl)-thiourea 
• 149-73-5 trimethyl orthoformate 
• 77287-34-4 formamide 
• 64-19-7 acetic acid 
• 1188-33-6 N,N-dimethylformamide diethyl diacetal 

Downstream Products

• 79377-22-3 N-[2-(1-ethyl-1H-[2]quinolyliden)-ethyliden]-p-anisidine; hydriodide 
• 113449-91-5 2-p-anisidinomethylene-N-(4-methoxy-phenyl)-malonamic acid ethyl ester 
• 1230-05-3 4-methoxy-N-[2-(3-methyl-3H-benzooxazol-2-ylidene)-ethylidene]-aniline 
• 1157-54-6 4-methoxy-N-[2-(3-methyl-3H-benzothiazol-2-ylidene)-ethylidene]-aniline 
• 99018-94-7 4-isobutyl-2-[2-(4-methoxy-anilino)-vinyl]-3,5-dimethyl-thiazolium; iodide 
• 109474-86-4 2-[2-(4-methoxy-anilino)-vinyl]-3,4,5-trimethyl-oxazolium; iodide 
• 109568-00-5 4-isobutyl-2-[2-(4-methoxy-anilino)-vinyl]-3,5-dimethyl-oxazolium; iodide 
• 1157-55-7 4-methoxy-N-[2-(3-methyl-3H-benzoselenazol-2-ylidene)-ethylidene]-aniline 
• 130685-72-2 4-Cyan-3-(4-methoxy-phenylamino)-benzo<4,5>thieno<2,3-c>pyridin-9,9-dioxid 
• 128799-71-3 N¹-(p-Chlorobenzoyl)-N¹,N²-di-(p-methoxyphenyl)-formamidine 
• 128799-72-4 N¹-Tosyl-N¹,N²-di(p-methoxyphenyl)-formamidine 
• 97968-72-4 1,5-Dihydro-5-(4-methoxyphenyl)-4H-pyrazolo<3,4-d>pyrimidin-4-one 
• 73187-66-3 3,5,6-trichloro-2-(4-methoxyphenylamino)-1,4-benzoquinone 
• 38756-10-4 4-methoxyphenylamino-(1,3-dioxo-2,3-dihydro-1H-inden-2-ylidene)ethanenitrile 

Relevant articles and documents

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Ultrasound promoted expeditious, catalyst-free and solvent-free approach for the synthesis of N,N′-diarylsubstituted formamidines at room temperature

An effortless and efficient protocol was developed for the synthesis of N,N′-diarylsubstituted formamidines under environment-friendly conditions. Ultrasonic energy was employed to obtain the desired products in excellent yields with high purity under solvent-free and catalyst-free conditions. Products were purified by the crystallization technique to avoid excess utilization of organic solvents.

Investigation of the reaction of 3,5-diamidino-4-nitropyrazole with amines

The interaction of 3,5-bis(N,N-dimethylaminomethylene)amino-1-methyl-4-nitropyrazole with amines proceeds regioselectively with the formation of 3-amino-5-(N,N-dimethylaminomethylene)amino-1- methyl-4-nitropyrazole. Amines are converted in this way into N

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Nanoporous TiO2 containing an ionic liquid bridge as an efficient and reusable catalyst for the synthesis of: N, N ′-diarylformamidines, benzoxazoles, benzothiazoles and benzimidazoles

In this work, a green and efficient procedure is reported for the preparation of N,N'-diarylformamidines, benzoxazoles, benzothiazoles, and benzimidazoles using nanoporous TiO2 containing an ionic liquid bridge. This reagent is prepared via the modification of nanoporous TiO2 with bis-3-(trimethoxysilylpropyl)-ammonium hydrogen sulfate (TiO2-[bip]-NH2+ HSO4-). The procedure gave the products in excellent yields in very short reaction times under solvent-free conditions. The reusability of the catalyst is the other important feature of the reported method.