Formation of Amidines from Aryliminodimagnesium and N,N-Dimethylformamide. Novel Catalytic Mediation by Single Electron Transfer with Use of Nitrobenzenes

DOI: 10.1246/cl.1990.1005

Source and publish data:

Chemistry Letters p. 1005 - 1008 (1990)

Update date:2022-08-30

Topics:

Authors:

Okubo, Masao

Tanaka, Mikio

Matsuo, Koji

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Article abstract of DOI:10.1246/cl.1990.1005

N,N'-Diarylformamidines were obtained in good yields by the reaction of aryliminodimagnesium (ArN(MgBr)2) with N,N-dimethylformamide in the presence of nitrobenzene.Novel catalytic mediation by single electron transfer was disclosed.

Full text of DOI:10.1246/cl.1990.1005

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