Formation of Amidines from Aryliminodimagnesium and N,N-Dimethylformamide. Novel Catalytic Mediation by Single Electron Transfer with Use of Nitrobenzenes

DOI: 10.1246/cl.1990.1005

Source and publish data:

Chemistry Letters p. 1005 - 1008 (1990)

Update date:2022-08-30

Topics:

Authors:

Okubo, Masao

Tanaka, Mikio

Matsuo, Koji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1005

N,N'-Diarylformamidines were obtained in good yields by the reaction of aryliminodimagnesium (ArN(MgBr)2) with N,N-dimethylformamide in the presence of nitrobenzene.Novel catalytic mediation by single electron transfer was disclosed.

Full text of DOI:10.1246/cl.1990.1005

Products guided by the article

Product name:Methanimidamide, N,N'-bis(4-methoxyphenyl)-

Cas No:1152-75-6

R&D Labs maybe for 1152-75-6

Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai

Relevant to this article

C2-Symmetric chiral diamine ligands for enantiomeric recognition of amino acid esters and mandelic acid by proton nmr titration method

Doi:10.3906/kim-1207-58
(2013)
Highly enantioselective Rh-catalyzed hydrogenations with heterocombinations of pentafluorobenzyl- and methoxybenzyl-derived binaphthyl phosphites

Doi:10.1016/j.tetlet.2007.11.201
(2008)
Discovery of O-(3-carbamimidoylphenyl)-l-serine amides as matriptase inhibitors using a fragment-linking approach

Doi:10.1016/j.bmcl.2014.12.008
(2015)
UTILISATION DE LA GUANIDINE COMME AGENT DESACETYLANT SELECTIF: UNE METHODE DE DESACETYLATION INSTANTANEE APPLICABLE AUX SUCRES

Doi:10.1016/S0040-4039(00)95538-2
(1987)
Stereospecific functionalization of iodoaziridines via unstabilized aziridinyllithiums generated by iodine-lithium exchange

Doi:10.1021/ol501024y
(2014)
Synthesis, characterization & biological studies of Mn(II), Fe(III) and Co(II) complexes of (Z)-1, 5-dimethyl-4-(2-(2-oxopropylidene) hydrazinyl)-2-phenyl-1H-pyrazol-3(2H)-one

Doi:10.1016/j.molstruc.2019.127110
(2020)

Article Doi