Formation of Amidines from Aryliminodimagnesium and N,N-Dimethylformamide. Novel Catalytic Mediation by Single Electron Transfer with Use of Nitrobenzenes

DOI: 10.1246/cl.1990.1005

Source and publish data:

Chemistry Letters p. 1005 - 1008 (1990)

Update date:2022-08-30

Topics:

Authors:

Okubo, Masao

Tanaka, Mikio

Matsuo, Koji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1005

N,N'-Diarylformamidines were obtained in good yields by the reaction of aryliminodimagnesium (ArN(MgBr)2) with N,N-dimethylformamide in the presence of nitrobenzene.Novel catalytic mediation by single electron transfer was disclosed.

Full text of DOI:10.1246/cl.1990.1005

Products guided by the article

Product name:Methanimidamide, N,N'-bis(4-methoxyphenyl)-

Cas No:1152-75-6

R&D Labs maybe for 1152-75-6

henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

website:http://www.jlpharms.com

Contact:86-571-86982636

Address:Rm A606, Fuyi Center, jianqiao street
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China

Relevant to this article

C2-Symmetric chiral diamine ligands for enantiomeric recognition of amino acid esters and mandelic acid by proton nmr titration method

Doi:10.3906/kim-1207-58
(2013)
Highly enantioselective Rh-catalyzed hydrogenations with heterocombinations of pentafluorobenzyl- and methoxybenzyl-derived binaphthyl phosphites

Doi:10.1016/j.tetlet.2007.11.201
(2008)
Discovery of O-(3-carbamimidoylphenyl)-l-serine amides as matriptase inhibitors using a fragment-linking approach

Doi:10.1016/j.bmcl.2014.12.008
(2015)
UTILISATION DE LA GUANIDINE COMME AGENT DESACETYLANT SELECTIF: UNE METHODE DE DESACETYLATION INSTANTANEE APPLICABLE AUX SUCRES

Doi:10.1016/S0040-4039(00)95538-2
(1987)
Stereospecific functionalization of iodoaziridines via unstabilized aziridinyllithiums generated by iodine-lithium exchange

Doi:10.1021/ol501024y
(2014)
Synthesis, characterization & biological studies of Mn(II), Fe(III) and Co(II) complexes of (Z)-1, 5-dimethyl-4-(2-(2-oxopropylidene) hydrazinyl)-2-phenyl-1H-pyrazol-3(2H)-one

Doi:10.1016/j.molstruc.2019.127110
(2020)

Article Doi