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115437-18-8

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  • 7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one,12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dodecahydro-6,9,11-trihydroxy-4a,8,13,13-tetramethyl-4-[(triethylsilyl)oxy]-,(2aR,4

    Cas No: 115437-18-8

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115437-18-8 Usage

Chemical Properties

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Uses

7-O-(Triethylsilyl)-10-deacetyl Baccatin III (cas# 115437-18-8_x000D_) is a compound useful in organic synthesis.

Check Digit Verification of cas no

The CAS Registry Mumber 115437-18-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,5,4,3 and 7 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 115437-18:
(8*1)+(7*1)+(6*5)+(5*4)+(4*3)+(3*7)+(2*1)+(1*8)=108
108 % 10 = 8
So 115437-18-8 is a valid CAS Registry Number.
InChI:InChI=1/C35H50O10Si/c1-9-46(10-2,11-3)45-24-17-25-34(19-42-25,44-21(5)36)28-30(43-31(40)22-15-13-12-14-16-22)35(41)18-23(37)20(4)26(32(35,6)7)27(38)29(39)33(24,28)8/h12-16,23-25,27-28,30,37-38,41H,9-11,17-19H2,1-8H3/t23-,24-,25+,27+,28?,30-,33+,34-,35+/m0/s1

115437-18-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 7-O-(Triethylsilyl)-10-deacetyl Baccatin III

1.2 Other means of identification

Product number -
Other names 7-O-triethylsilyl-10-DAB

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
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More Details:115437-18-8 SDS

115437-18-8Relevant articles and documents

Synthesis of modified baccatins via an oxidation-reduction protocol

Appendino, Giovanni,Jakupovic, Jasmin,Cravotto, Giancarlo,Enriu, Renata,Varese, Marcella,Bombardelli, Ezio

, p. 3233 - 3236 (1995)

(12R)-7-trietylsilyl-11-dihydro-10-deacetylbaccatin III (2), -deacetylbaccatin III (4) and the 7,8-seco baccatin III (5a) were synthesized from 10-deacetylbaccatin III via an oxidation-reduction protocol.

A facile one-pot synthesis of 7-triethylsilylbaccatin III

Baloglu, Erkan,Miller, Michael L.,Cavanagh, Emily E.,Marien, Tracy P.,Roller, Elizabeth E.,Chari, Ravi V. J.

, p. 817 - 818 (2005)

A one-pot synthesis of 7-triethylsilylbaccatin III has been delineated. The reaction can easily be extended for the preparation of analogs of baccatin III.

A Highly Efficient, Practical Approach to Natural Taxol

Denis, Jean-Noel,Greene, Andrew E.

, p. 5917 - 5919 (1988)

-

β-Selective Aroylation of Activated Alkenes by Photoredox Catalysis

Lei, Zhen,Banerjee, Arghya,Kusevska, Elena,Rizzo, Eric,Liu, Peng,Ngai, Ming-Yu

supporting information, p. 7318 - 7323 (2019/04/30)

Late-stage synthesis of α,β-unsaturated aryl ketones remains an unmet challenge in organic synthesis. Reported herein is a photocatalytic non-chain-radical aroyl chlorination of alkenes by a 1,3-chlorine atom shift to form β-chloroketones as masked enones

Preparation method of taxane compound and intermediate of taxane compound

-

Paragraph 0155; 0156; 0157; 0158; 0159; 0160, (2017/08/29)

The invention provides a preparation method of a taxane compound and an intermediate of the taxane compound. The preparation method of a TPI-287 intermediate A starts with a starting step of a raw material 10-deacetylbaccatin III (also named as 10-DAB), a

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