116027-51-1Relevant articles and documents
A synthesis of α-amino acids via direct reductive carboxylation of imines with carbon dioxide
Sathe, Ajay A.,Hartline, Douglas R.,Radosevich, Alexander T.
, p. 5040 - 5042 (2013/06/05)
A method for the synthesis of α-amino acids by direct reductive carboxylation of aromatic imines with CO2 is described. The protocol employs readily available commercial reagents and serves as a one-step alternative to the Strecker synthesis. The Royal Society of Chemistry 2013.
Highly chemoselective crossed imino pinacol coupling reaction using the synergetic effect of boron trifluoride etherate and trichloromethylsilane
Shimizu, Makoto,Suzuki, Ikuhiro,Makino, Hiroaki
, p. 1635 - 1638 (2007/10/03)
Use of boron trifluoride etherate and trichloromethylsilane in the presence of zinc-copper couple effects a crossed imino pinacol coupling reaction to give 1,2-diamines in good yields with high diastereoselectivities.
Reductive dimerization and reduction of imines using lanthanum metal
Nishino, Toshiki,Nishiyama, Yutaka,Sonoda, Noboru
, p. 131 - 135 (2007/10/03)
The treatment of N-benzylideneaniline (1a) with a half-equivalent of lanthanum metal and a catalytic amount of iodine gave the reductive dimerization product of 1a, a vic-diamine, in good yield. Various vic-diamines were synthesized from aldimines in this