1613-89-4

Basic information

• Product Name: Benzenamine, 4-chloro-N-(phenylmethylene)-, (E)-
• CAS NO: 1613-89-4
• Molecular Formula: C13H10ClN
• Molecular Weight: 215.682
• Mol File: 1613-89-4.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-chloro-N-(phenylmethylene)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-chloro-N-(phenylmethylene)-, (E)-(1613-89-4)
• EPA Substance Registry System: Benzenamine, 4-chloro-N-(phenylmethylene)-, (E)-(1613-89-4)

Safety Data

• Hazardous Substances Data: 1613-89-4(Hazardous Substances Data)

Upstream product

• 102002-37-9 2-(4-Chloro-phenylamino)-1,2-diphenyl-ethanol 
• 100-00-5 4-chlorobenzonitrile 
• 106-47-8 4-chloro-aniline 
• 100-51-6 benzyl alcohol 
• 100-46-9 benzylamine 
• 19865-58-8 N-(4-chlorophenyl)-α-phenylnitrone 
• 3296-05-7 1-azido-4-chlorobenzene 
• 108-88-3 toluene 
• 2948-39-2 N,N'-bis-(4-chloro-phenyl)-bibenzyl-α,α'-diyldiamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 4686-05-9 2-(N-(4-chloroanilino))-2-phenylacetonitrile 
• 95005-60-0 3-(N-p-chlorophenylamino)-2-methyl-1,3-diphenyl-1-propanone 
• 102002-37-9 2-(4-Chloro-phenylamino)-1,2-diphenyl-ethanol 
• 6633-64-3 ethyl 6-chloro-2-phenylquinoline-4-carboxylate 
• 2948-39-2 N,N'-bis-(4-chloro-phenyl)-bibenzyl-α,α'-diyldiamine 
• 116027-51-1 N,N-bis-(4-methoxyphenyl)-1,2-diphenylethane-1,2-diamine 

Relevant articles and documents

Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones

Chemoselective reduction of imines to secondary amines is catalyzed efficiently by tethered and untethered, half-sandwich ruthenium N-heterocyclic carbene (NHC) complexes at room temperature. The untethered Ru-NHC complexes are more efficient as catalysts for the reduction of aldimines and ketimines than the tethered complexes. Using the best untethered complex as a catalyst, electronic and steric demands on the reaction was probed using a series of imines. Chemoselectivity of the catalyst towards imine reduction was tested by performing inter and intramolecular competitive reactions in a variety of ways. The catalyst exhibits a very high TON and TOF under anaerobic conditions.

Synergistic Photoredox Catalysis and Organocatalysis for Inverse Hydroboration of Imines

The first catalytic inverse hydroboration of imines with N-heterocyclic carbene (NHC) boranes has been realized by means of cooperative organocatalysis and photocatalysis. This catalytic combination provides a promising platform for promoting NHC-boryl radical chemistry under sustainable and radical-initiator-free conditions. The highly important functional-group compatibility and possible application in late-stage hydroborations represent an important step forward to an enhanced α-amino organoboron library.

Rhodium-catalyzed synthesis of imines and esters from benzyl alcohols and nitroarenes: Change in catalyst reactivity depending on the presence or absence of the phosphine ligand

The [Rh(COD)Cl]2/xantphos/Cs2CO3 system efficiently catalyzes the reductive N-alkylation of aryl nitro compounds with alcohols by a borrowing-hydrogen strategy to afford the corresponding imine products in good to excellent yields. In the absence of xantphos, the [Rh(COD)Cl]2/Cs2CO3 catalytic system behaves as an effective catalyst for the dehydrogenative coupling of alcohols to esters, with nitrobenzene as a hydrogen acceptor. The reactivity of the rhodium catalytic system can be easily manipulated to selectively afford the imine or ester.