117858-84-1

Basic information

• Product Name: N-benzyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-ribitol
• Synonyms: N-benzyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-ribitol
• CAS NO: 117858-84-1
• Molecular Weight: 263.337
• Mol File: 117858-84-1.mol

Chemical Properties

• CAS DataBase Reference: N-benzyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-ribitol(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-ribitol(117858-84-1)
• EPA Substance Registry System: N-benzyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-ribitol(117858-84-1)

Safety Data

• Hazardous Substances Data: 117858-84-1(Hazardous Substances Data)

Upstream product

• 117859-47-9 N-benzyl-1,4-dideoxy-5,6-O-isopropylidene-1,4-imino-D-allitol 
• 67642-42-6 2,3,5,6-di-O-isopropylidene-D-gulono-1,4-lactone 
• 117859-45-7 methanesulfonic acid (S)-((4R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-((4S,5S)-5-methanesulfonyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl ester 
• 117858-83-0 N-benzyl-1,4-dideoxy-2,3:5,6-di-O-isopropylidene-1,4-imino-D-allitol 
• 3969-61-7 2,3:5,6-di-O-isopropylidene-D-gulitol 

Downstream Products

• 153172-30-6 1-amino-1,4-anhydro-N-benzyl-5-O-tertbutyldimethylsilyl-1-deoxy-2,3-O-isopropylidene-D-ribitol 
• 105990-41-8 (2R,3R,4S)-2-hydroxymethylpyrrolidine-3,4-diol 
• 117770-18-0 N-benzyl-1,4-dideoxy-1,4-imino-D-ribitol 
• 153172-31-7 (3aR,4R,6aS)-4-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)tetrahydro-2,2-dimethyl-3aH-[1,3]dioxolo[4,5-c]pyrrole 
• 153172-33-9 (3aR,4R,6aS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole 
• 153172-34-0 (3aR,4R,6S,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-6-phenyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole 
• 153172-36-2 (3aR,4R,6S,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-6-[2-phenylsulfanyl-3-(2-trimethylsilanyl-ethoxymethyl)-3H-imidazol-4-yl]-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole 
• 117770-19-1 N-benzyl-1,4-dideoxy-1,4-imino-D-ribitol trifluoroacetate 
• 1338787-19-1 (3S,4S)-1-benzyl-5-chloro-3,4-dihydroxy-3,4-O-isopropylidenepiperidine 
• 1338787-20-4 N-benzyl-4-deoxy-2,3-O-isopropylidene-5-O-methanesulfonyl-D-ribono-1,4-lactam 
• 1338787-22-6 S-(N-benzyl-4,5-dideoxy-2,3-O-isopropylidene-D-ribono-1,4-lactam-5-yl)-N-(tert-butoxycarbonyl)-1-homocysteine tert-butyl ester 
• 1338787-23-7 S-(N-benzyl-4,5-dideoxy-D-ribono-1,4-lactam-5-yl)-1-homocysteine 
• 1338787-29-3 4-amino-4-deoxy-D-ribose O-benzyloxime 
• 192317-22-9 N-benzyl-4-deoxy-2,3-O-isopropylidene-D-ribono-1,4-lactam 

Relevant articles and documents

POLYHYDROXYLATED PYRROLIDINES FROM SUGAR LACTONES: SYNTHESIS OF 1,4-DIDEOXY-1,4-IMINO-D-GLUCITOL FROM D-GALACTONOLACTONE AND SYNTHESES OF 1,4-DIDEOXY-1,4-IMINO-D-ALLITOL, 1,4-DIDEOXY-1,4-IMINO-D-RIBITOL, AND (2S,3R,4S)-3,4-DIHYDROXYPROLINE FROM D-GULONOLACTONE

The use of readily available sugar lactones in the synthesis of polyhydroxylated pyrrolidines is illustrated by the preparation of the glucosidase inhibitor 1,4-dideoxy-1,4-imino-D-glucitol from D-galactonolactone and by the conversion of D-gulonolactone into 1,4-dideoxy-1,4-imino-D-allitol, 1,4-dideoxy-1,4-imino-D-ribitol, and (2S,3R,4S)-3,4-dihydroxyproline.