1191925-09-3Relevant articles and documents
5-Bromomethyl-4,5-dihydroisoxazoles
Mosher, Michael D.,Norman, Amber L.,Shurrush, Khriesto A.
, p. 5647 - 5648 (2009)
The preparation of substituted 4,5-dihydroisoxazoles can be accomplished via the treatment of β,γ-unsaturated oximes with liquid bromine. The reaction provides a convenient route to the highly functionalized title compounds.
General 5-Halomethyl Isoxazoline Synthesis Enabled by Copper-Catalyzed Oxyhalogenation of Alkenes
Li, Xiaoqing,Ding, Yu,Qian, Lijie,Gao, Yang,Wang, Xinqiang,Yan, Xinhuan,Xu, Xiangsheng
, p. 12656 - 12663 (2019)
A general and efficient oxyhalogenation of unsaturated ketoximes has been achieved through copper catalysis with diethyl bromomalonate, N-chlorosuccinimide, and N-iodosuccinimide, yielding 5-chloromethyl, 5-bromomethyl, and 5-iodomethyl isoxazolines in go
Synthesizing method of halogenated isoxazoline type compound
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Paragraph 0061-0064, (2019/11/13)
The invention discloses a synthesizing method of a halogenated isoxazoline type compound, and belongs to the field of organic synthesis. According to the synthesizing method, under the inert gas protection condition, a ketoxime type compound and an organi
Transition-metal-free oxychlorination of alkenyl oximes:: In situ generated radicals with tert -butyl nitrite
Zhang, Xiao-Wei,Xiao, Zu-Feng,Wang, Mei-Mei,Zhuang, Yan-Jun,Kang, Yan-Biao
supporting information, p. 7275 - 7281 (2016/08/05)
Oxychlorination of alkenyl oximes is harder compared to the analogous oxybromination or oxyiodination because of the difficulty associated with the formation of chlorine cations or radicals. A transition-metal-free oxychlorination of alkenyl oximes has be
Oxime-mediated oxychlorination and oxybromination of unactivated olefins
Dong, Kui-Yong,Qin, Hai-Tao,Liu, Feng,Zhu, Chen
supporting information, p. 1419 - 1422 (2015/03/04)
An oxime-mediated oxychlorination and oxybromination of unactivated olefins relying on palladium catalysis has been developed. A wide range of chlorinated and brominated isoxazolines has been synthesized in moderate to good yields. To demonstrate the value of the method, the brominated isoxazoline has been further converted to other useful synthetic feedstock.