119244-56-3Relevant academic research and scientific papers
A general and stereoselective method for synthesis of tri- and tetrasubstituted alkenes
Macia?giewicz,Dybowski,Skowrońska
, p. 6057 - 6066 (2007/10/03)
A convenient, general and stereoselective synthesis of trisubstituted alkenes and tetrasubstituted alkenes containing a cyanide function as well as trisubstituted episulphides have been elaborated. Methodology described for the preparation of these compounds is based on the corresponding readily available selenophosphates 1 and thiophosphates 2.
A new synthesis of tri- and tetrasubstituted olefins based on thio- and selenophosphates
Skowronska,Maciagiewicz,Dybowski,Krawczyk,Owsianik
, p. 409 - 412 (2007/10/03)
Stereoselective synthesis of tri- and tetrasubstituted functionalized olefins and new phosphates bearing functionalized cyclic substituent has been developed using thiophosphates and selenophosphates as key intermediates.
Cleavage of Carbon-Carbon Bonds with High Stereochemical Control. 6. Asymmetric Synthesis of Chiral C-Centered Organosilanes by Haller-Bauer Cleavage of Optically Active, Nonenolizable α-Silyl Phenyl Ketones
Gilday, John P.,Gallucci, Judith C.,Paquette, Leo A.
, p. 1399 - 1408 (2007/10/02)
Sequential alkylation and methylation of l-menthyl ester 10 provides diastereomeric mixtures in which 12 is slighthly enhanced over 13.Conversely, C-silation and alkylation of propionate ester 11 delivers 13 in excess.In either cause, a single chromatogra
