119340-78-2

Basic information

• Product Name: 2-benzyl-2-trimethylsilyl-1,3-dithiane
• Synonyms: 2-benzyl-2-trimethylsilyl-1,3-dithiane
• CAS NO: 119340-78-2
• Molecular Weight: 282.546
• Mol File: 119340-78-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-benzyl-2-trimethylsilyl-1,3-dithiane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-2-trimethylsilyl-1,3-dithiane(119340-78-2)
• EPA Substance Registry System: 2-benzyl-2-trimethylsilyl-1,3-dithiane(119340-78-2)

Safety Data

• Hazardous Substances Data: 119340-78-2(Hazardous Substances Data)

Upstream product

• 505-23-7 1,3 dithiane 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 
• 31593-52-9 2-benzyl-1,3-dithiane 
• 122-78-1 phenylacetaldehyde 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 56583-94-9 (phenylacetyl)trimethylsilane 
• 1372129-45-7 C₁₇H₁₅NO₄ 
• 1372129-57-1 C₁₇H₁₅NO₄ 
• 1372129-60-6 (Z)-methyl 3-(4-methoxyphenyl)-2-methyl-4-phenyl-2-butenoate 
• 665004-92-2 (Z)-2-methyl-3-trimethylsilyl-4-phenyl-2-butenoic acid 
• 1416889-51-4 (2S,3R)-4-nitro-2,3-diphenyl-1-(trimethylsilyl)butan-1-one 
• 7500-45-0 N-benzylphenylacetamide 
• 5460-60-6 N-phenethyl-2-phenylacetamide 

Relevant articles and documents

Intermolecular Schmidt reaction of alkyl azides with acyl silanes

The first intermolecular Schmidt reaction of alkyl azides with acyl silanes has been designed and realized, producing a range of amides with absolute site selectivity in good to excellent yields. The mechanism of the conversion has been proposed, and the reaction exhibits scope of substrates.

Palladium-catalyzed fluoride-free cross-coupling of intramolecularly activated alkenylsilanes and alkenylgermanes: Synthesis of tamoxifen as a synthetic application

We have demonstrated that intramolecular hypercoordination of a carboxylic acid is a powerful activation strategy for the palladium-catalyzed cross-coupling reaction of trialkyl(vinyl)silanes and trialkyl(vinyl)germanes under fluoride-free conditions. Z-β-Trialkylsilyl- and Z-β- trialkylgermylacrylic acids, synthesized stereoselectively by olefination with ynolates, are highly stable and useful reagents for cross-coupling with a variety of aryl iodides to provide tetrasubstituted olefins possessing different carbon substituents in a stereocontrolled and diversity-oriented manner. An application to a stereoselective synthesis of (Z)-tamoxifen is also reported. Copyright

Substituted silyl alkylene amines

This invention relates to substituted silyl alkylene amines, to the intermediates and processes useful for their preparation, to their pharmacological use as MAO-B inhibitors and to their end-use application in the treatment of Parkinson's Disease and senile dementia of Alzheimer's type.