1198-01-2

Basic information

• Product Name: Stannane, trimethyl(1-phenylethenyl)-
• CAS NO: 1198-01-2
• Molecular Formula: C11H16Sn
• Molecular Weight: 266.958
• Mol File: 1198-01-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Stannane, trimethyl(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, trimethyl(1-phenylethenyl)-(1198-01-2)
• EPA Substance Registry System: Stannane, trimethyl(1-phenylethenyl)-(1198-01-2)

Safety Data

• Hazardous Substances Data: 1198-01-2(Hazardous Substances Data)

Upstream product

• 98-81-7 1-bromovinylbenzene 
• 1066-45-1 trimethyltin(IV)chloride 
• 1066-44-0 trimethyltin bromide 
• 67300-99-6 1-phenylethenylmagnesium bromide 
• 28143-79-5 1-phenyl vinyl triflate 
• 917-54-4 methyllithium 

Downstream Products

• 208983-73-7 2-styrylnicotinic acid methyl ester 
• 14064-48-3 (E)-3-methylstilbene 
• 1066-45-1 trimethyltin(IV)chloride 
• 120726-16-1 Me₃SnCHPhCH₂PPh₂ 
• 96130-36-8 (C₆H₅)((CH₃)3Sn)CHCH₂(Sn(CH₃)3) 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 627510-84-3 3-nitro-2-[(E)-2-phenylethenyl]pyridine 
• 74309-58-3 1-phenyl-1-(3-pyridyl)ethylene 
• 2633-06-9 (E)-3-(2-phenylvinyl)pyridine 
• 15260-65-8 2-(1-phenylvinyl)pyridine 
• 645-49-8 cis-stilben 
• 114646-77-4 1-(6-methyl-2,5-diphenyl-3,4-dihydro-2H-pyran-2-yl)ethanone 
• 4452-11-3 1,2-diphenylprop-2-en-1-one 
• 404393-77-7 1-[5-acetyl-1-benzyl-4-(1-phenyl-vinyl)-1,4-dihydro-pyridin-3-yl]-2,2,2-trichloro-ethanone 

Relevant articles and documents

REGIO- AND STREREO-SELECTIVE SYNTHESIS OF VINYLSTANNANES. TRANSITION-METAL CATALYZED STANNYLMETALATION OF ACETYLENES AND CONVERSION OF ENOL TRIFLATES AND VINYL IODIDES INTO VINYLSTANNANES

Two new methods for the regio- and strereo-selective synthesis of vinylstannanes are described. (i) The reaction of terminal acetylenes with n-Bu3SnMgMe, n-Bu3SnAlEt2, or (n-Bu3Sn)2Zn in the presence of various transition-metal catalysts provides vinylstannanes in good yields.Whereas copper-catalyzed stannylmagnesation of 4-benzyloxy-1-butyne gives (E)-4-benzyloxy-1-tributylstannyl-1-butene exclusively, palladium-catalyzed stannylzincation affords 4-benzyloxy-2-tributylstannyl-1-butene preferentially. (ii) Treatment of enol triflates or vinyl iodide with Me3Sn-MgMe in the presence of CuCN catalyst gives vinylstannanes in good yields.