120927-58-4

Upstream product

• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 
• 100-39-0 benzyl bromide 
• 13265-84-4 D-glucal 
• 137792-57-5 3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-D-glucal 
• 207564-33-8 (2S,3S,4R)-3,4-Bis-benzyloxy-3,4-dihydro-2H-pyran-2-carbaldehyde 
• 58871-10-6 3,4-di-O-benzyl-D-glucal 
• 27784-76-5 tert-butyl diethylphosphonoacetate 
• 67-56-1 methanol 
• 137792-58-6 (E)-3-((2R,3S,4R)-3,4-Bis-benzyloxy-3,4-dihydro-2H-pyran-2-yl)-acrylic acid tert-butyl ester 

Downstream Products

• 120927-65-3 <3aR-(3aα,4α,5β,6β,6aα)>-5,6-Bis(benzyloxy)hexahydro-4-(1,1'-dimethoxymethyl)-2H-cyclopentafuran-2-one 
• 120964-39-8 (1R,3S,4S,5R,6R,7S)-5,6-Bis(benzyloxy)-3-methoxy-2-oxabicyclo<2.2.1>heptane-7-acetic Acid tert-Butyl Ester 
• 120927-62-0 (1R,3S,4S,5R,6R,7R)-5,6-Bis(benzyloxy)-3-methoxy-2-oxabicyclo<2.2.1>heptane-7-acetic Acid tert-Butyl Ester 
• 120927-62-0 ((1S,3S,4R,5R,6S,7S)-5,6-Bis-benzyloxy-3-methoxy-2-oxa-bicyclo[2.2.1]hept-7-yl)-acetic acid tert-butyl ester 
• 120927-62-0 ((1S,3S,4R,5R,6S,7R)-5,6-Bis-benzyloxy-3-methoxy-2-oxa-bicyclo[2.2.1]hept-7-yl)-acetic acid tert-butyl ester 

Relevant academic research and scientific papers

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on