120927-65-3

Upstream product

• 67-56-1 methanol 
• 120927-62-0 (1R,3S,4S,5R,6R,7R)-5,6-Bis(benzyloxy)-3-methoxy-2-oxabicyclo<2.2.1>heptane-7-acetic Acid tert-Butyl Ester 
• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 
• 100-39-0 benzyl bromide 
• 58871-10-6 3,4-di-O-benzyl-D-glucal 
• 120927-58-4 (Z)-3-((3R,4S,5S,6S)-3,4-Bis-benzyloxy-5-iodo-6-methoxy-tetrahydro-pyran-2-yl)-acrylic acid tert-butyl ester 
• 120927-58-4 (E)-3-((3R,4S,5S,6S)-3,4-Bis-benzyloxy-5-iodo-6-methoxy-tetrahydro-pyran-2-yl)-acrylic acid tert-butyl ester 
• 13265-84-4 D-glucal 
• 120927-58-4 tert-Butyl (Methyl 3,4-di-O-benzyl-2,6,7-trideoxy-2-iodo-α-D-manno-oct-6(E)-eno-1,5-pyranosid)uronate 
• 120927-63-1 tert-Butyl (Methyl 3,4-di-O-benzyl-2,6,7-trideoxy-2-iodo-α-D-manno-oct-6(Z)-eno-1,5-pyranosid)uronate 
• 137792-57-5 3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-D-glucal 
• 137792-58-6 (E)-3-((2R,3S,4R)-3,4-Bis-benzyloxy-3,4-dihydro-2H-pyran-2-yl)-acrylic acid tert-butyl ester 
• 207564-33-8 (2S,3S,4R)-3,4-Bis-benzyloxy-3,4-dihydro-2H-pyran-2-carbaldehyde 

Relevant academic research and scientific papers

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on

Intramolecular Radical Cyclizations of 2-Deoxy-2-iodohexopyranoside Derivatives: Routes to Densely Functionalized Carbocycles.

2-Deoxy-2-iodohexopyranosides containing appropriate traps at C6 or C7 undergo radical cyclization to give oxabicyclo or systems whose glicosidic bonds are readily cleaved to afford densely functionalized cyclopentanes or cyclohexanes.