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121089-46-1

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121089-46-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 121089-46-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,1,0,8 and 9 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 121089-46:
(8*1)+(7*2)+(6*1)+(5*0)+(4*8)+(3*9)+(2*4)+(1*6)=101
101 % 10 = 1
So 121089-46-1 is a valid CAS Registry Number.

121089-46-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (2-but-3-enylphenyl)methanol

1.2 Other means of identification

Product number -
Other names Benzenemethanol,2-(3-butenyl)-(9CI)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:121089-46-1 SDS

121089-46-1Relevant articles and documents

Organoselenium and DMAP co-catalysis: Regioselective synthesis of medium-sized halolactones and bromooxepanes from unactivated alkenes

Verma, Ajay,Jana, Sadhan,Prasad, Ch. Durga,Yadav, Abhimanyu,Kumar, Sangit

supporting information, p. 4179 - 4182 (2016/03/19)

A catalytic system consisting of bis(4-methoxyphenyl)selenide and 4-(dimethylamino)pyridine (DMAP) has been developed for the regioselective synthesis of medium-sized bromo/iodo lactones and bromooxepanes possessing high transannular strain. 77Se NMR, mass spectrometry and theoretical studies reveal that the reaction proceeds via a quaternary selenium intermediate.

Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation

Ammann, Stephen E.,Rice, Grant T.,White, M. Christina

, p. 10834 - 10837 (2014/08/18)

The synthesis of chroman, isochroman, and pyran motifs has been accomplished via a combination of Pd(II)/bis-sulfoxide C-H activation and Lewis acid co-catalysis. A wide range of alcohols are found to be competent nucleophiles for the transformation under uniform conditions (catalyst, solvent, temperature). Mechanistic studies suggest that the reaction proceeds via initial C-H activation followed by a novel inner-sphere functionalization pathway. Consistent with this, the reaction shows reactivity trends orthogonal to those of traditional Pd(0)-catalyzed allylic substitutions.

Palladium-catalyzed intramolecular carboesterification of olefins

Li, Yang,Jardine, Katherine J.,Tan, Runyu,Song, Datong,Dong, Vy M.

supporting information; experimental part, p. 9690 - 9692 (2010/04/28)

One catalyst three bonds: The title reaction between propiolic acids and unactivated olefins (see scheme; O red, Cl green) results in vicinal functionalization of the olefin, with the formation of new C-C and C-O bonds. Structurally complex 6,7,5-tricyclic ring systems are formed in a single step by this cascade chloropalladation and formal [3+2] cycloaddition.

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