121091-30-3

Basic information

• Product Name: 1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE
• Synonyms: 1,3-DIMETHYL-IMIDAZOLIUM TRIFLUORMETHASULFONATE;1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE;1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHYLSULFONATE;[C1MIm]TfS
• CAS NO: 121091-30-3
• Molecular Formula: CF₃O₃S*C₅H₉N₂
• Molecular Weight: 246.21
• Mol File: 121091-30-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE(121091-30-3)
• EPA Substance Registry System: 1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE(121091-30-3)

Safety Data

• Hazardous Substances Data: 121091-30-3(Hazardous Substances Data)

Usage

General Description

1,3-Dimethylimidazolium trifluoromethanesulfonate is a chemical compound with the molecular formula C5H10F3N2O3S. It is a type of imidazolium salt, which is commonly used as a conductive material in electrochemistry and as a catalyst in organic synthesis. 1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE is known for its high thermal stability and solubility in polar solvents, making it an attractive option for various industrial applications. In addition, 1,3-Dimethylimidazolium trifluoromethanesulfonate has been studied for its potential use as a solvent in the extraction of aromatic hydrocarbons and for its antimicrobial properties. However, it is important to handle this compound with caution, as it is toxic and can cause irritation to the skin, eyes, and respiratory system.

InChI:InChI=1/C5H9N2.CHF3O3S/c1-6-3-4-7(2)5-6;2-1(3,4)8(5,6)7/h3-5H,1-2H3;(H,5,6,7)/q+1;/p-1

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 333-27-7 methyl trifluoromethanesulfonate 
• 4333-62-4 1,3-dimethylimidazolim iodide 
• 38542-94-8 CF₃O₃S^(1-)*H⁽¹⁺⁾*H₃N 
• 3970-21-6 2-Methoxyethoxymethyl chloride 

Downstream Products

• 74-85-1 ethene 
• 6596-81-2 1,3-dimethylimidazole-2-thione 
• 70-55-3 toluene-4-sulfonamide 
• 121091-37-0 C₁₂H₁₃N₃S 
• 486-25-9 9-fluorenone 
• 746-47-4 tetrabenzo[5.5]fulvalene 

Relevant articles and documents

Synthesis of ionic liquids equipped with 2-methoxyethoxymethyl/methoxymethyl groups using a simple microreactor system

A simple microreactor system has been utilized for the continuous flow synthesis of novel ionic liquids having a (2-methoxyethoxy)methyl or methoxymethyl substituent. Conversion rates of N-bases and tributylphosphine in the microreactor system are faster than those in the batch system because of less diffusion distance in the tube reactor. This method allows us to prepare ionic liquids in efficient yields with high purity.

N-Heterocyclic Carbene Catalyzed Photoenolization/Diels–Alder Reaction of Acid Fluorides

The combination of light activation and N-heterocyclic carbene (NHC) organocatalysis has enabled the use of acid fluorides as substrates in a UVA-light-mediated photochemical transformation previously observed only with aromatic aldehydes and ketones. Stoichiometric studies and TD-DFT calculations support a mechanism involving the photoactivation of an ortho-toluoyl azolium intermediate, which exhibits “ketone-like” photochemical reactivity under UVA irradiation. Using this photo-NHC catalysis approach, a novel photoenolization/Diels–Alder (PEDA) process was developed that leads to diverse isochroman-1-one derivatives.

Imidazolium ionic liquids: A simple anion exchange protocol

An efficient and simple protocol was developed to obtain quantitative iodide or bromide exchange for a broad range of anions in imidazolium ionic liquids. Selected anions were loaded in an anion exchange resin using two different procedures and were then used to provide a pure convenient ion pair. The Royal Society of Chemistry 2009.