1212-50-6

Usage

InChI:InChI=1/C15H14O/c16-12-15-10-8-14(9-11-15)7-6-13-4-2-1-3-5-13/h1-5,8-12H,6-7H2

Upstream product

• 201230-82-2 carbon monoxide 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 83168-79-0 1-phenyl-2-(trifluorosilyl)ethane 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 80676-35-3 1-(chloromethyl)-4-(2-phenylethyl)benzene 
• 32555-96-7 4-styrylbenzaldehyde 
• 100-42-5 styrene 
• 104-88-1 4-chlorobenzaldehyde 
• 1122-91-4 4-bromo-benzaldehyde 
• 17376-04-4 2-phenethyl iodide 
• 14310-24-8 1-bromo-4-(2-phenylethyl)benzene 
• 68-12-2 N,N-dimethyl-formamide 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 4714-24-3 1-bromo-4-styrylbenzene 

Downstream Products

• 93319-05-2 3-<4-Phenethyl-phenyl>-acrylsaeure 
• 3507-04-8 1-Phenyl-2-(4-<(N-Methyl-morpholinio)-acetylhydrazonomethyl>-phenyl)-ethan iodid 
• 3731-90-6 1-Phenyl-2-<4-(4-hydroxy-phenyliminomethyl)-phenyl>-aethan 
• 3525-66-4 1-Phenyl-2-(4-cyclohexyliminomethyl-phenyl)-aethan 
• 3525-55-1 1-Phenyl-2-<4-(4-methoxy-phenyliminomethyl)-phenyl>-aethan 
• 3782-73-8 1-Phenyl-2-<4-(4-carboxy-phenyliminomethyl)-phenyl>-ethan 
• 3782-81-8 1-Phenyl-2-<4-(4-ethoxycarbonyl-phenyliminomethyl)-phenyl>-ethan 
• 3731-80-4 1-Phenyl-2-<4-(3-hydroxy-4-methoxycarbonyl-phenyliminomethyl)-phenyl>-aethan 
• 1334304-94-7 N-(4-(phenylethyl)phenylmethylene)-2-naphthalenamine 

Relevant academic research and scientific papers

Copper(II)-catalyzed preparation of alkylindium compounds and applications in cross-coupling reactions both in aqueous media

An efficient water-based method for the synthesis of alkylindium compound in the presence of a catalytic amount of cheap and readily available CuSO4·5H2O (10 mol%) was developed. The thus-generated alkylindium compounds effectively underwent palladium-catalyzed cross-coupling reactions with a myriad of aryl halides in aqueous media, leading to the cross-coupled products in modest to high yields. The mildness of the formed alkyl organometallics allowed the tolerance to various important functional groups incorporated in both substrates of alkyl iodides and aryl halides.

Application of novel coupling reaction to preparing carbon-carbon bond structured compounds

The invention relates to application of a novel coupling reaction to preparing carbon-carbon bond structured compounds and mainly provides a reaction between alkyl indium compounds and halides. The reaction between the alkyl indium compounds and the halides can produce corresponding carbon-carbon structured products. The novel coupling reaction is high in process yield, broad in functional group tolerance and good in compatibility.

Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.

Preparation of Alkyl Indium Reagents by Iodine-Catalyzed Direct Indium Insertion and Their Applications in Cross-Coupling Reactions

An efficient method for the synthesis of alkyl indium reagent by means of an iodine-catalyzed direct indium insertion into alkyl iodide in THF is reported. The thus-generated alkyl indium reagents effectively underwent Pd-catalyzed cross-coupling reactions with various aryl halides, exhibiting good compatibility to a variety of sensitive functional groups. By replacing THF with DMA and using 0.75 equiv of iodine, less reactive alkyl bromide could be used as substrate for indium insertion with equal ease.

Cesium carbonate-catalyzed indium insertion into alkyl iodides and their synthetic utilities in cross-coupling reactions

A catalytic amount of cesium carbonate (10?mol%) was found to be capable of effectively catalyzing the insertion of indium powder into alkyl iodides. The thus-generated alkyl indium reagents could readily undergo palladium-catalyzed cross-coupling reactions with a wide variety of aryl halides, showing compatibility to a range of important functional groups.

OXACAZONE COMPOUNDS TO TREAT CLOSTRIDIUM DIFFICILE

Compounds, compositions, and methods for treating C. difficile are provided.

Catalytic asymmetric hydrogenation using a [2.2]paracyclophane based chiral 1,2,3-triazol-5-ylidene-Pd complex under ambient conditions and 1 atmosphere of H2

Chiral 1,2,3-triazol-5-ylidene-Pd complexes with the planar chiral [2.2]paracyclophane wing tip group have been synthesized and structurally characterized. The complex with a labile acetonitrile co-ligand is an excellent catalyst for chemoselective hydrogenation of alkynes and alkenes and enantioselective hydrogenation of prochiral alkenes at ambient conditions and 1.0 atmosphere of H2.

METHOD FOR PRODUCING 4,4'-DIFORMYLDIPHENYLALKANE

A method for producing a 4,4'-diformyldiphenylalkane represented by the following formula (2), containing formylating a diphenylalkane represented by the following formula (1) with carbon monoxide in the presence of hydrogen fluoride and boron trifluoride, in which the reaction temperature of the formylation is from -50 to 5°C, from 5 to 30 mol of hydrogen fluoride is used per 1 mol of the diphenylalkane, and from 1.5 to 5 mol of boron trifluoride is used per 1 mol of the diphenylalkane: wherein R represents an alkanediyl group having from 1 to 6 carbon atoms, wherein R represents an alkanediyl group having from 1 to 6 carbon atoms.

Palladium porphyrin catalyzed hydrogenation of alkynes: Stereoselective synthesis of cis -alkenes

(Tetraphenylporphyrin)palladium was developed as a catalyst for the chemoselective and stereoselective hydrogenation of alkynes to cis-alkenes by the syn-addition of hydrogen. Alkynes containing various functional groups were tolerated in the reaction, which gave the corresponding cis-alkenes in good to excellent yields. Georg Thieme Verlag Stuttgart New York.

Incorporation of steroidal biomarkers into petroleum model compounds

A series of fully-substituted 5,6-benzoquinolines covalently fused to the chlolestane framework has been synthesized to serve as model compounds for the poorly characterized components found in the heaviest fractions of petroleum, namely the asphaltenes.