122-91-8Relevant articles and documents
Selective Production of Diethyl Maleate via Oxidative Cleavage of Lignin Aromatic Unit
Cai, Zhenping,Long, Jinxing,Li, Yingwen,Ye, Lin,Yin, Biaolin,France, Liam John,Dong, Juncai,Zheng, Lirong,He, Hongyan,Liu, Sijie,Tsang, Shik Chi Edman,Li, Xuehui
supporting information, p. 2365 - 2377 (2019/09/10)
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Application of polydopamine sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (Fe3O4@PDA-SO3H) as a heterogeneous and recyclable nanocatalyst for the formylation of alcohols and amines under solvent-free conditions
Taheri, Sepideh,Veisi, Hojat,Hekmati, Malak
, p. 5075 - 5081 (2017/07/11)
Herein, formylation of structurally different amines and alcohols with ethyl formate was carried out in the presence of a catalytic proportion of sulfonic acid supported on polydopamine (PDA)-encapsulated Fe3O4 nanoparticles as a heterogeneous, recyclable, and greatly efficient catalyst; this method provided the corresponding N-formyl compounds in good to excellent yields under solvent-free conditions. The magnetically catalytic system was recovered, by-passing the time-consuming filtration operation using an external magnet device. This procedure also increases the purity of the product and promises economic and ecological advantages. Furthermore, the recovery and reuse of the catalyst was demonstrated five times without detectable loss in the activity.
Br?nsted acidic ionic liquid supported on rice husk ash (RHA-[pmim]HSO4): A highly efficient and reusable catalyst for the formylation of amines and alcohols
Shirini, Farhad,Seddighi, Mohadeseh,Mamaghani, Manouchehr
, p. 50631 - 50638 (2014/12/10)
In this work, rice husk ash (RHA), as a natural source of amorphous silica, was used as a support for the immobilization of 1-methyl-3-(trimethoxysilylpropyl)-imidazolium hydrogen sulfate. The immobilized acidic ionic liquid was characterized with a variety of techniques including infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and pH analysis. The catalytic performance of this heterogeneous ionic liquid was probed for the N-formylation of a variety of amines using formic acid under solvent free conditions. It is also useful for the formylation of benzylic alcohols. The procedure gave the products in excellent yields in very short reaction times. Also this catalyst can be reused ten times without loss of its catalytic activity.