122501-60-4Relevant academic research and scientific papers
Asymmetric Synthesis of (-)-Actinonin and (-)-epi-Actinonin
Bashiardes, George,Bodwell, Graham J.,Davies, Stephen G.
, p. 459 - 470 (2007/10/02)
The highly asymmetric induction imparted by the iron chiral auxiliary 5-C5H5)Fe(CO)(PPh3)> is exploited in the preparation of homochiral (R)- and (S)-α-pentylsuccinates.Their application in the synthesis of (-)-actinonin and (-)-epi-actinoni
THE ASYMMETRIC SYNTHESIS OF (-)-ACTINONIN USING THE IRON CHIRAL AUXILIARY 5-C5H5)Fe(CO)(PPh3)>
Bashiardes, George,Davies, Stephen G.
, p. 6509 - 6512 (2007/10/02)
The asymmetric synthesis of the α-pentyl succinate fragment of (-)-Actinonin is achived using the chiral ironacetyl S-(+)-5-C5H5)-Fe(CO)(PPh3)COCH3> and subsequently converted to (-)-Actinonin in an overall yield of 41percent.
