1233144-56-3

Basic information

• Product Name: acetic acid (E)-3-(2,4,6-trimethyl-phenyl)-allyl ester
• Synonyms: acetic acid (E)-3-(2,4,6-trimethyl-phenyl)-allyl ester
• CAS NO: 1233144-56-3
• Molecular Weight: 218.296
• Mol File: 1233144-56-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: acetic acid (E)-3-(2,4,6-trimethyl-phenyl)-allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: acetic acid (E)-3-(2,4,6-trimethyl-phenyl)-allyl ester(1233144-56-3)
• EPA Substance Registry System: acetic acid (E)-3-(2,4,6-trimethyl-phenyl)-allyl ester(1233144-56-3)

Safety Data

• Hazardous Substances Data: 1233144-56-3(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 480-63-7 mesitylenecarboxylic acid 
• 108-67-8 1,3,5-trimethyl-benzene 
• 4028-63-1 iodomesitylene 
• 1221972-05-9 acetic acid 1-(2,4,6-trimethyl-phenyl)-allyl ester 

Downstream Products

• 1394213-80-9 (E)-2-(hexa-1,5-dienyl)-1,3,5-trimethylbenzene 

Relevant articles and documents

S,O-ligand-promoted palladium-catalyzed C–H olefination of arenes with allylic substrates

An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone.

Triflimide-catalyzed allyl-allyl cross-coupling: A metal-free allylic alkylation

A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.