123629-22-1Relevant articles and documents
The remarkable effect of a simple ion: Iodide-promoted transfer hydrogenation of heteroaromatics
Wu, Jianjun,Wang, Chao,Tang, Weijun,Pettman, Alan,Xiao, Jianliang
, p. 9525 - 9529 (2012)
I can do it! Accelerated by simple iodide ions, rhodium-catalysed transfer hydrogenation can be readily performed on quinolines, isoquinolines and quinoxalines, affording the tetrahydro products in high yields with low catalyst loading (see scheme). Copyright
Chiral phosphoric acid catalyzed oxidative kinetic resolution of cyclic secondary amine derivatives including tetrahydroquinolines by hydrogen transfer to imines
Saito, Kodai,Miyashita, Hiromitsu,Akiyama, Takahiko
supporting information, p. 16648 - 16651 (2015/11/25)
A chiral Bronsted acid catalyzed dehydrogenative kinetic resolution of tetrahydroquinoline derivatives, which are representative of cyclic secondary amines, based on their hydrogen transfer to aromatic imines was efficiently achieved with high enantioselectivities. This hydrogen transfer of tetrahydroquinolines to imines was not driven by their aromatization to quinolines. This dehydrogenative kinetic resolution could be also applied to the asymmetric synthesis of various benzofused heterocycles containing secondary amine cores.
PH-regulated asymmetrie transfer hydrogenation of quinolines in water
Wang, Chao,Li, Chaoqun,Wu, Xiaofeng,Xiao, Jianliang,Pettman, Alan
supporting information; experimental part, p. 6524 - 6528 (2009/12/26)
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