123820-52-0

Basic information

• Product Name: ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane
• CAS NO: 123820-52-0
• Molecular Weight: 250.413
• Mol File: 123820-52-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane(123820-52-0)
• EPA Substance Registry System: ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane(123820-52-0)

Safety Data

• Hazardous Substances Data: 123820-52-0(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 75-77-4 chloro-trimethyl-silane 
• 29393-16-6 methyl 2-methyl-3-phenylpropionate 
• 69688-50-2 Methyl 2-methyl-2-chloro-3-phenylpropionate 

Relevant articles and documents

C?Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes

A new family of carbon-bound boron enolates, generated by a kinetically controlled halogen exchange between chlorocatecholborane and silylketene acetals, is described. These C?boron enolates are demonstrated to activate 1,3-enyne substrates in the presence of a Pd0/Senphos ligand complex, resulting in the first examples of a carboboration reaction of an alkyne with enolate-equivalent nucleophiles. Highly substituted dienyl boron building blocks are produced in excellent site-, regio-, and diastereoselectivity by the described catalytic cis-carboboration reaction.