123992-10-9Relevant academic research and scientific papers
Stereopentads derived from a sequence of Mukaiyama aldolization and free radical reduction on α-methyl-β-alkoxy aldehydes: A general strategy for efficient polypropionate synthesis
Brazeau, Jean-Fran?ois,Mochirian, Philippe,Prévost, Michel,Guindon, Yvan
supporting information; scheme or table, p. 64 - 74 (2009/04/07)
(Chemical Equation Presented) In a stereodivergent manner, all 16 diastereomeric stereopentads 7-22 were synthesized starting with α-methyl-β-alkoxy aldehydes 25 and 27. We designed an approach based on a sequence of a Mukaiyama aldolization with enoxysil
The total synthesis of oleandomycin
Tatsuta,Ishiyama,Tajima,Koguchi,Gunji
, p. 709 - 712 (2007/10/02)
The key aglycone, oleandolide, has been synthesized by coupling two segments of C1-C7 and C8-C14 portions, which are enantiospecifically derived from methyl α-L- and D-rhamnosides, respectively.
Development of a fully synthetic stereoselective route to 6-Deoxyerythronolide B by reiterative applications of the Lewis acid catalyzed diene aldehyde cyclocondensation reaction: A remarkable instance of diastereofacial selectivity
Myles,Danishefsky,Schulte
, p. 1636 - 1648 (2007/10/02)
The synthesis of racemic 2, which contains the relative stereochemistry appropriate to a synthesis of (9S)-dihydro-6-deoxyerythronolide B (see compound 38), is described. The synthesis features three Lewis acid catalyzed diene aldehyde cyclocondensation r
