124604-08-6Relevant academic research and scientific papers
Highly efficient cross-dehydrogenative-coupling between ethers and active methylene compounds
Zhang, Yuhua,Li, Chao-Jun
, p. 1949 - 1952 (2006)
(Chemical Equation Presented) An unlikely couple: C-C bonds can be formed between ethers and methylene compounds by cross-dehydrogenative-coupling (see scheme; DDQ = 2,3-dichloro-5,6-dicyanobenzoquinone). This straightforward reaction employs mild conditi
Electrochemical Cyclodimerization of Alkylidenemalonates
Elinson, Michail N.,Feducovich, Sergey K.,Zakharenkov, Alexandre A.,Ugrak, Bogdan I.,Nikishin, Gennady I.,et al.
, p. 5035 - 5046 (2007/10/02)
Electrolysis of dimethyl alkylidenemalonates RCH=C(COOMe)2 (R=n-Alk, Ph) in an undivided cell in MeOH in the presence of alkali metal halide as mediator, leads to the formation of cyclic dimers, i.e., 3,4-disubstituted 1,1,2,2-cyclobutanetetracarboxylates.The reaction proceeds via the reductive coupling of two substrate molecules at cathode and the cyclization of a hydrodimer dianion by its interaction with an active form of a mediator, an anode-generated halogen.
Electrochemical Hydroxylation, Methoxylation, and Hydroxymethylation of Active Methine Compounds
Kawabata, Jin-ichi,Nozawa, Koohei,Kawai, Ken-ichi,Nakajima, Shoichi
, p. 181 - 183 (2007/10/02)
Hydroxylation, methoxylation, or hydroxymethylation at the active methine group of phenylmalonate, benzylmalonate and diphenylacetate were achieved by anodic oxidation.
