125066-14-0Relevant articles and documents
A Metal-Free Synthesis of 2-Alkyl(or Aryl) Thiomethyl-2-cyclohexenones from Cyclic Morita–Baylis–Hillman Bromides
Baioui, Narjes,Abidi, Ahlem,Rezgui, Farhat
, p. 704 - 709 (2016/09/20)
Under mild conditions, an efficient and rapid S-allylation of thiols with cyclic Morita–Baylis–Hillman (MBH) bromides without the need of a transition-metal catalyst or an expensive additive is described herein. Treatment of the MBH bromides with various
A General Synthesis of 2-Substituted Cyclohex-2-enones
Armitage, Mark A.,Lathbury, David C.,Mitchell, Michael B.
, p. 1551 - 1552 (2007/10/02)
A new synthesis of 2-substituted cyclohex-2-enones has been achieved using a sequence involving the aldol reaction of the aluminium enolate derived from thiolate addition to cyclohex-2-enone, followed by dehydration, rearrangement and desulfurisation.
NEW SUBSTITUTION REACTION OF ALLYLIC NITRO COMPOUNDS. REGIOSELECTIVE REPLACEMENT OF NITRO GROUP IN CYCLIC α-(NITROALKYL)ENONES BY NUCLEOPHILES
Tamura, Rui,Tamai, Shinobu,Suzuki, Hitomi
, p. 2413 - 2416 (2007/10/02)
Regioselective replacement of nitro group in cyclic α-(nitroalkyl)-enones by various nucleophiles such as stabilized carbanions, amine, NaN3, PhSO2Na and PhSNa provides the overall SN2 type products.
