31863-60-2

Upstream product

• 33740-53-3 2-Ethyl-2-cyclohexenol 
• 67-56-1 methanol 
• 80222-59-9 2-chloro-2-ethylcyclohexanone 
• 75-15-0 carbon disulfide 
• 98559-75-2 oct-5t-enoyl chloride 
• 7646-78-8 tin(IV) chloride 
• 16424-53-6 trans-5-octenoic acid 
• 86119-84-8 phosphoric acid 
• 7664-93-9 sulfuric acid 
• 98559-24-1 1-ethyl-6-bromo-cyclohexene 
• 4423-94-3 2-ethylcyclohexanone 
• 74457-11-7 2-(1-Hydroxy-ethyl)-3-phenylsulfanyl-cyclohexanone 
• 930-68-7 cyclohexenone 
• 60-29-7 diethyl ether 

Downstream Products

• 113088-70-3 3-Chloro-2-ethyl-cyclohex-2-enol 
• 113088-66-7 2-Chloro-3-ethyl-cyclohexa-1,3-dienecarbaldehyde 
• 4423-94-3 (R)-(-)-2-ethylcyclohexan-1-one 
• 75599-12-1 (S)-(+)-2-ethylcyclohexan-1-one 
• 3274-96-2 2-ethylcyclohexanol 
• 1446394-34-8 C₁₇H₂₂OS 
• 120950-96-1 cis-2-ethyl-3-trimethylsilylcyclohexanone 
• 63075-56-9 2-ethyl-3-methyl-cyclohexanone 

Relevant academic research and scientific papers

From vinyl pyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization

Starting from vinyl pyranoses an iron-catalyzed tandem isomerization- intramolecular aldolization reaction was developed to prepare cyclohexenone derivatives bearing substituents on the double bond, and it has been applied in a short synthesis of 4-epi-ga

Facile synthesis of c/s-2-alkyl-3-trialkylsilyloxycycloalkanones via the non-aldol aldol rearrangement of 2,3-epoxycycloalkanols

Silyl triflate-promoted rearrangement of c/s-2,3-epoxycycloalkanols A, prepared by epoxidation of the cyclic allylic alcohol and then sllylatlon, afforded good yields (～70-75%) of the c/s-2-alkyl-3-silyloxycycloalkanones B, presumably via the intermediates C and D, even with quite large α-substituents, e.g., terf-butyl. Finally, it has been shown that the stereochemistry of the epoxy alcohol is crucial as one would expect from the mechanism.

(2-hydroxy)ethyl-thioureas useful as modulators of alpha2B adrenergic receptors

Compounds of formula (i) and of formula (ii) wherein the symbols have the meaning disclosed in the specification, specifically or selectively modulate α2B and/or α2C adrenergic receptors in preference over α2A adrenergic receptors, and as such are useful for alleviating chronic pain and allodynia and have no or only minimal cardivascular and/or sedatory activity.

A General Synthesis of 2-Substituted Cyclohex-2-enones

A new synthesis of 2-substituted cyclohex-2-enones has been achieved using a sequence involving the aldol reaction of the aluminium enolate derived from thiolate addition to cyclohex-2-enone, followed by dehydration, rearrangement and desulfurisation.

FeCl3-CATALYZED OXIGENATION OF 2-HALOCYCLOHEXANONES TO ADIPIC ACID DIESTERS

Ferric chloride-catalyzed aerobic oxygenation of 2-halocyclohexanones in methanol to yield adipic acid dimethyl esters.