1256554-06-9Relevant academic research and scientific papers
Highly enantioselective reduction of β-amino nitroolefins with a simple n-sulfinyl urea as bifunctional catalyst
Liu, Xiang-Wei,Yan, Yan,Wang, Yong-Qiang,Wang, Chao,Sun, Jian
, p. 9204 - 9207 (2012/08/27)
Simple but effective: A structurally simple N-sulfinyl urea was found to be a highly efficient bifunctional catalyst, which allows for the development of a novel pathway for the construction of chiral β-amino nitroalkanes through enantioselective reduction of β-amino nitroolefins by trichlorosilane. High yields and excellent enantioselectivities were obtained for a broad range of β-arylamino nitroolefin substrates (see scheme). Copyright
