125706-42-5

Basic information

• Product Name: Acetic acid, [(4-chlorophenyl)sulfinyl]-, (S)-
• CAS NO: 125706-42-5
• Molecular Formula: C8H7ClO3S
• Molecular Weight: 218.661
• Mol File: 125706-42-5.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(4-chlorophenyl)sulfinyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(4-chlorophenyl)sulfinyl]-, (S)-(125706-42-5)
• EPA Substance Registry System: Acetic acid, [(4-chlorophenyl)sulfinyl]-, (S)-(125706-42-5)

Safety Data

• Hazardous Substances Data: 125706-42-5(Hazardous Substances Data)

Upstream product

• 1569-69-3 Cyclohexanethiol 
• 106-54-7 p-Chlorothiophenol 
• 73281-90-0 methyl 4-chlorophenylsulfinylacetate 
• 15446-15-8 methyl 2-[(4-chlorophenyl)thio]acetate 
• 125706-40-3 (+/-)-Methyl (cyclohexylsulfinyl)acetate 
• 14091-31-7 methyl 2-(cyclohexylthio)acetate 

Downstream Products

• 137761-05-8 (1S,2R)-2-phenylcyclohexanyl (S)-4-chlorophenylsulfinylacetate 
• 137761-03-6 (1R,2S,5R)-8-phenylmenthyl (S)-4-chlorophenylsulfinylacetate 
• 137761-02-5 (1S,2R,5S)-menthyl (S)-4-chlorophenylsulfinylacetate 

Relevant articles and documents

Continuous flow biocatalytic resolutions of methyl sulfinylacetates

Product inhibition was encountered for some substrates in the resolution of methyl sulfinylacetates mediated by lipase Amano AK, so an apparatus to continually extract the carboxylate product was devised. This was applied to resolve some sulfoxides with h

Biocatalytic Resolutions of Sulfinylalkanoates: A Facile Route to Optically Active Sulfoxides

Two methods are presented for kinetic resolutions of compounds containing ester and sulfoxide functionalities (sulfinylalkanoates).In the first a crude lipase preparation from Pseudomonas sp. (K 10) mediates enantioselective hydrolysis of these esters in

A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES

Biocatalytic resolution of methyl sulfinylacetates afford sulfoxides (R)-(1)-(6) in very high optical yields; the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of γ-hydroxy-α,β-unsaturated esters.