125715-24-4

Basic information

• Product Name: Benzenemethanol, 2-nitro-a-2-propenyl-
• CAS NO: 125715-24-4
• Molecular Formula: C10H11NO3
• Molecular Weight: 193.202
• Mol File: 125715-24-4.mol
• Article Data: 47

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-nitro-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-nitro-a-2-propenyl-(125715-24-4)
• EPA Substance Registry System: Benzenemethanol, 2-nitro-a-2-propenyl-(125715-24-4)

Safety Data

• Hazardous Substances Data: 125715-24-4(Hazardous Substances Data)

Upstream product

• 552-89-6 2-nitro-benzaldehyde 
• 591-87-7 Allyl acetate 
• 1027922-45-7 1-nitro-2-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene 
• 7393-43-3 tetraallyl tin 
• 1730-25-2 allylmagnesium bromide 
• 107-18-6 allyl alcohol 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 217805-03-3 tris-4,4,5,5,6,6,7,7,7-nonafluoroheptyl allyl stannane 
• 556-56-9 allyl iodid 
• 762-72-1 allyl-trimethyl-silane 
• 2551-83-9 allyltrimethoxysilane 

Downstream Products

• 168329-41-7 1-(2-nitrophenyl)propane-1,3-diol 
• 205369-82-0 3-buten-1-(2-nitrophenyl) 1-N,N-bis(2-chloroethyl)phosphordiamidate 
• 881416-95-1 2-(1-methoxymethoxybut-3-enyl)nitrobenzene 
• 1424832-40-5 1-(2-nitrophenyl)-3-(N-methyl-N-tritylamino)propanol 
• 1402073-75-9 1-(2-nitrophenyl)-3-(N-methyl-N-tritylamino)propyl 1H-imidazole-1-carboxylate 
• 17418-09-6 4-hydroxy-4-(2-nitrophenyl)butan-2-one 
• 42075-26-3 4-(2-nitrophenyl)-4-oxobutanoic acid 
• 1424832-38-1 C₁₀H₁₄N₂O₃ 
• 194221-59-5 3-[Bis-(4-methoxy-phenyl)-phenyl-methoxy]-3-(2-nitro-phenyl)-propan-1-ol 
• 168329-40-6 Diisopropyl-phosphoramidous acid 3-[bis-(4-methoxy-phenyl)-phenyl-methoxy]-1-(2-nitro-phenyl)-propyl ester 2-cyano-ethyl ester 
• 168329-42-8 3-[Bis-(4-methoxy-phenyl)-phenyl-methoxy]-1-(2-nitro-phenyl)-propan-1-ol 
• 181210-18-4 Dimethyl-[1-(toluene-4-sulfonyl)-2,3,4,5-tetrahydro-1H-benzo[b]azepin-5-yl]-amine 
• 24310-36-9 1-tosyl-2,3,4,5-tetrahydro-1H-1-benzazepin-5-one 
• 881417-04-5 N-{2-[1-(N-phthalimidoyl)-4-(tetrahydropyran-2-yloxy)butyl]phenyl}-p-toluenesulfonamide 

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Copper-Impregnated Magnesium-Lanthanum Mixed Oxide: A Reusable Heterogeneous Catalyst for Allylation of Aldehydes and Ketones

Copper-impregnated magnesium-lanthanum mixed oxide [Cu(II)/Mg?La] was used as catalyst in synthesis of homoallylic alcohols from aldehydes and ketones using allyltributylstannane as the allylating source. The present protocol provides a great application

Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes

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Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

The ruthenium-catalyzed allylation of aldehydes with allylic pro-nucleophiles has been demonstrated to be an efficient means to form carbon-carbon bonds under mild conditions. The evolution of this reaction from the initial serendipitous discovery to its general synthetic scope is detailed, highlighting the roles of water, CO, and amine in the generation of a more complete catalytic cycle. The use of unsymmetrical allylic pro-nucleophiles was shown to give preferential product formation through the modulation of reaction conditions. Both (E)-cinnamyl acetate and vinyl oxirane were efficiently used to form the anti-branched products (up to >20:1 anti/syn) and E-linear products (up to >20:1 E/Z) in high selectivity with aromatic, α,β-unsaturated, and aliphatic aldehydes, respectively. Attempts to render the reaction enantioselective are highlighted and include enantioenrichment of up to 75:25 for benzaldehyde.