126218-83-5

Basic information

• Product Name: Benzene, 1-bromo-2-[(R)-methylsulfinyl]-
• CAS NO: 126218-83-5
• Molecular Formula: C7H7BrOS
• Molecular Weight: 219.102
• Mol File: 126218-83-5.mol
• Article Data: 128

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-2-[(R)-methylsulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-2-[(R)-methylsulfinyl]-(126218-83-5)
• EPA Substance Registry System: Benzene, 1-bromo-2-[(R)-methylsulfinyl]-(126218-83-5)

Safety Data

• Hazardous Substances Data: 126218-83-5(Hazardous Substances Data)

Upstream product

• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 19614-16-5 2-bromo-1-(methylsulfanyl)benzene 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 917-64-6 methyl magnesium iodide 
• 126218-83-5 1-bromo-2-(methylsulfinyl)benzene 
• 89581-50-0 ortho-bromobenzenesulfinic acid 
• 583-55-1 1-Bromo-2-iodobenzene 
• 6320-02-1 o-bromothiophenol 
• 67-68-5 dimethyl sulfoxide 
• 164021-74-3 (1S,2R)-(-)-2-[N-(3’,5’-di-tert-butylsalicylidene)amino]-1,2-diphenylethanol 
• 615-36-1 2-bromoaniline 
• 103053-00-5 2-bromobenzenesulfinyl chloride 
• 33733-73-2 3-bromo-1-(methylthio)benzene 

Downstream Products

• 395090-42-3 2-(methylsulfinyl)phenyl phenyl ether 
• 833459-47-5 (2-bromophenyl)(imino)(methyl)-λ⁶-sulfanone 
• 33951-33-6 1-bromo-2-(methylsulfonyl)benzene 
• 7321-58-6 (S)-methyl o-bromophenyl sulfoxide 
• 7321-58-6 (R)-2-bromophenyl methyl sulfoxide 
• 1171926-64-9 (7-bromo-1-benzothiophen-2-yl)methanol 
• 19614-16-5 2-bromo-1-(methylsulfanyl)benzene 
• 573-57-9 1,4-dihydronaphthalene-1,4-epoxide 
• 1669-98-3 Ethyl methyl sulfoxide 
• 107344-54-7 1-<2-(Methylsulfinyl)phenyl>pyrrole 
• 241-34-9 benzo[1, 2-b: 4, 5-b']bis[b]benzothiophene 

Relevant articles and documents

Photocatalyzed sulfide oxygenation with water as the unique oxygen atom source

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Four inorganic-organic hybrid octa-Cu cluster sandwiched polyoxotungstates (POTs), [Cu8(H2O)2(en)4(B-α-H2SiW9O34)2] (1), [Cu8(H2O)2(en)4(B-α-H2GeW9O34)2] (2), K2[Cu8(en)4(B-α-HSiW9O34)2]·6H2O (3), and K2[Cu8(en)4(B-α-HGeW9O34)2]·2H2O (4) (en = ethylenediamine), were hydrothermally made and characterized by single-crystal X-ray diffraction, infrared spectra, powder X-ray diffraction, and thermogravimetric analysis, respectively. Structure analysis reveals that the polyoxoanion of 1/2 is a discrete dimer built by two trivalent Keggin [B-α-XW9O34]10- (X = Si/Ge) fragments and one octa-Cu cluster, whereas 3 and 4 display a two-dimensional network built by octa-Cu-sandwiched POT units via substitution of coordinated water on polyanions of 1 and 2 and further expand into a three-dimensional framework via K cation bridges. Ultraviolet-visible diffuse reflectance spectra reveal that 1-4 are potential semiconductor materials. Moreover, its visible light-driven catalytic H2 evolution activity, electrochemical properties, catalysis for oxygenation reactions of thioethers, and magnetic behaviors have been investigated in detail.

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A SeO3-centered lacunary Keggin-type heteropolyoxovanadate (hetero-POV) K6H2[SeV10O28(SeO3)3]?14 H2O (1) was isolated by one-pot reaction of KVO3 and SeOsu

A Bimetallic Ag/Ti-Based Coordination Polymer as a Catalyst for Electrocatalytic CO2 Reduction and Selective Sulfide Oxidation

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Catalyst-free visible light-mediated selective oxidation of sulfides into sulfoxides under clean conditions

A facile and efficient visible-light-mediated method for directly converting sulfides into sulfoxides under clean conditions without using any photocatalysts is reported. This method exhibited favourable compatibility with functional groups and afforded a series of sulfoxides with high selectivity and yields. Moreover, in order to shed more light on such a transformation, detailed mechanism studies were carried out both experimentally and theoretically. The readily accessible, low-cost and eco-friendly nature of the developed method will endow it with attractive applications in chemical synthesis.