126597-34-0

Basic information

• Product Name: 1-p-hydroxyphenyl-1-phenyl-1-ethanol
• Synonyms: 1-p-hydroxyphenyl-1-phenyl-1-ethanol
• CAS NO: 126597-34-0
• Molecular Weight: 214.264
• Mol File: 126597-34-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-p-hydroxyphenyl-1-phenyl-1-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-hydroxyphenyl-1-phenyl-1-ethanol(126597-34-0)
• EPA Substance Registry System: 1-p-hydroxyphenyl-1-phenyl-1-ethanol(126597-34-0)

Safety Data

• Hazardous Substances Data: 126597-34-0(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 108-95-2 phenol 
• 17256-00-7 1-(4-hydroxyphenyl)-1-phenylethylene 
• 100-52-7 benzaldehyde 
• 108-86-1 bromobenzene 
• 99-93-4 4-Hydroxyacetophenone 
• 100-58-3 phenylmagnesium bromide 
• 16635-23-7 phenyltriisopropoxytitanium(IV) 

Downstream Products

• 120346-43-2 4-(1-phenylethyl)phenol 
• 120346-43-2 1-(4-hydroxyphenyl)-1-phenylethane 
• 1029-77-2 1-Phenyl-1-(4-trimethylsiloxy)-phenylaethan 
• 17256-00-7 1-(4-hydroxyphenyl)-1-phenylethylene 
• 1190958-01-0 1-acetyl[1,1'-biphenyl]-4(1H)-one 

Relevant articles and documents

m-Quinone methides from m-hydroxy-1,1-diaryl alkenes via excited-state (formal) intramolecular proton transfer mediated by a water trimer [16]

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COMPOUNDS

The invention relates to difluorocyclopropane compounds, methods for their manufacture, and their uses for example as medicaments. According to one aspect, there is provided a compound of general formula (I): wherein X and Y are phenyl groups, one of which is substituted by an ethoxyamine basic side chain; R1 and R2 are independently selected from H or a C1-C6 alkyl group; and wherein one or each of X and Y, and the or each C1-C6 alkyl group, are optionally substituted or further substituted by one or more alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl or alkylamino radicals of 1 to 20 carbon atoms, and/or by one or more fluoro, chloro, bromo, iodo, hydroxy, oxyalkyl, amino, aminoalkyloraminodialkyl radicals.

Catalytic Asymmetric 1,6-Conjugate Addition of para-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters

Described herein is a general and mild catalytic asymmetric 1,6-conjugate addition of para-quinone methides (p-QMs), a class of challenging reactions with previous limited success. Benefiting from chiral Bronsted acid catalysis, which allows in situ formation of p-QMs, our reaction expands the scope to general p-QMs with various substitution patterns. It also enables efficient intermolecular formation of all-carbon quaternary stereocenters with high enantioselectivity.