Tetrahedron Letters p. 4953 - 4956 (1989)
Update date:2022-08-04
Topics:
Chhen, A.
Vaultier, M.
Carrie, R.
Ylides derived from ω-azidoalkyltriphenylphosphonium salts were generated at low temperature.They are stable at -80 deg C for several hours and react smoothly and stereospecifically with typical aldehydes to form Z-ω-azido olefins which are the precursors of ω-unsaturated primary and secondary amines.
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