127820-39-7

Basic information

• Product Name: tris(4-chlorophenyl)sulfonium trifluoromethanesulfonate
• Synonyms: tris(4-chlorophenyl)sulfonium trifluoromethanesulfonate
• CAS NO: 127820-39-7
• Molecular Weight: 515.789
• Mol File: 127820-39-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(4-chlorophenyl)sulfonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4-chlorophenyl)sulfonium trifluoromethanesulfonate(127820-39-7)
• EPA Substance Registry System: tris(4-chlorophenyl)sulfonium trifluoromethanesulfonate(127820-39-7)

Safety Data

• Hazardous Substances Data: 127820-39-7(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 3085-42-5 bis(4-chlorophenyl)sulfoxide 
• 108-90-7 chlorobenzene 

Downstream Products

• 39672-21-4 1-(4-methoxyphenyl)-2-(4-chlorophenyl)acetylene 
• 145013-56-5 6-chloro-3-(4-chlorophenyl)-4H-chromen-4-one 
• 1047389-42-3 3-(4-chlorophenyl)-6-fluoro-4H-chromen-4-one 
• 130252-76-5 3-(4-chlorophenyl)-6-methyl-4H-chromen-4-one 
• 132351-67-8 3-(4-chlorophenyl)-4H-1-benzopyran-4-one 
• 1044066-84-3 1-chloro-4-(3-phenylpropoxy)benzene 
• 32605-98-4 3-chloro-N-cyclohexylaniline 
• 56506-61-7 4-chloro-N-cyclohexylaniline 

Relevant articles and documents

Sonogashira reaction using arylsulfonium salts as cross-coupling partners

Triarylsulfonium, alkyl- and fluoroalkyl(diaryl)-sulfonium, and aryl(dialkyl)sulfonium triflates are successfully used as a new family of cross-coupling participants in the Sonogashira reaction as aryldiazonium, diaryliodonium, and tetraphenylphosphonium salts. It was found that terminal alkynes reacted mildly with triarylsulfonium or (2,2,2-trifluoroethyl)diphenylsulfonium triflate at room temperature under Pdand Cu-cocatalysis to give the corresponding arylalkynes in up to >99% yield. This protocol represents the first use of arylsulfonium salts as cross-coupling partners in the Pd/Cu-catalyzed Sonogashira reaction.