1279017-84-3

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 5195-29-9 4-bromophenylglyoxal 
• 7099-87-8 4-bromophenylglyoxylic acid 
• 99-90-1 para-bromoacetophenone 
• 62551-73-9 2-oxo-2-(4-bromophenyl)acetyl chloride 
• 75-65-0 tert-butyl alcohol 
• 106-37-6 1.4-dibromobenzene 
• 50624-94-7 oxalic acid tert-butyl ester ethyl ester 

Downstream Products

• 1463489-36-2 tert-butyl (Z)-2-((2-methoxy-4-nitrophenyl)imino)-2-(4-bromophenyl)acetate 
• 1279018-09-5 (S)-tert-butyl 2-(4-bromophenyl)-2-((S)-3,4-dichloro-2,5-dihydro-5-oxofuran-2-yl)-2-hydroxyacetate 
• 1279018-28-8 (S)-tert-butyl 2-(4-bromophenyl)-2-((S)-3,4-dibromo-5-oxo-2,5-dihydrofuran-2-yl)-2-hydroxyacetate 

Relevant academic research and scientific papers

2-Oxo-Driven Coupling Reactions of 2-Oxo Aldehydes/2-Oxo Iminium Ions and Hydroperoxides at Room Temperature

An efficient 2-oxo-group-promoted direct coupling reaction between 2-oxo aldehydes and hydroperoxides has been developed. The method has been used successfully for the generation of different 2-oxo esters and acids. This reaction harnesses the hydrogen-bonding-induced self-decomposition tendency of hydroperoxides; the intermediates produced by this process then attack the aldehyde or iminium ion to generate cross-coupled products either by direct coupling or by an amine-catalysed pathway. No external oxidants or metal catalysts are required for our method, and the reaction takes place at room temperature.

Organocatalytic Enantioselective Michael Reaction of Malononitrile with β,β-Disubstituted Nitroalkenes

We have developed and optimized an enantioselective Michael reaction of malononitrile with β,β-disubstituted nitroalkenes. This reaction was catalyzed by a cinchona alkaloid derived thiourea catalyst, producing products of high yields (up to 98 %) and ste

Amino Acid Salt Catalyzed Asymmetric Synthesis of 1,2-Diols with A Quaternary Carbon Center

Enantioenriched 1,2-diols with a quaternary carbon center have great potential in the preparation of natural and biologically active compounds, but remain challenging synthetic targets which demand for both good diastereo- and enantioselectivity. As part

Chemo- and enantioselective Bronsted acid-catalyzed reduction of α-imino esters with catecholborane

The chemo- and enantioselective reduction of α-imino esters with catecholborane has been developed employing 10 mol% of an enantiopure BINOL-based phosphoric acid as organocatalyst. Various differently substituted aromatic α-amino acid derivatives can be