129222-62-4Relevant academic research and scientific papers
Photogenerated Neutral Nitrogen Radical Catalyzed Bifunctionalization of Alkenes
Zhao, Quan-Qing,Chen, Jun,Zhou, Xue-Song,Yu, Xiao-Ye,Chen, Jia-Rong,Xiao, Wen-Jing
, p. 8024 - 8029 (2019)
Alkene bifunctionalizations are powerful tools for the rapid construction of structurally complex and valuable scaffolds, and such reactions typically involve the use of transition-metal catalysts or organocatalysts. Here, we report for the first time a p
Free radical addition reactions of allylic sulfones to alkenes
Harvey, Iain W.,Phillips, Eifion D.,Whitham, Gordon H.
, p. 6493 - 6508 (2007/10/03)
Intermolecular radical reactions involving formal addition of the sulfonyl and allyl fragments of an allylic sulfone across the double bond of an alkene are described. Reactions are most successful when the allylic sulfone has an electron withdrawing group at the 2-position. Only monosubstituted alkenes give useful yields of adducts, though both electron withdrawing and electron donating substituents are effective.
Intermolecular Carbon-Carbon Bond forming Reactions involving Allylic Sulphones
Harvey, Iain W.,Phillips, Eifion D.,Whitham, Gordon H.
, p. 481 - 482 (2007/10/02)
Adducts (3) are formed in satisfactory yield from allylic sulphones (2) and monosubstituted alkenes (1) under free radical conditions provided that the X substituent in the sulphone is electron withdrawing.
