1293294-90-2Relevant academic research and scientific papers
Facile synthesis of 4-vinyl- and 4-fluorovinyl-1,2,3-triazoles via bifunctional "click-olefination" reagents
Kumar, Rakesh,Pradhan, Padmanava,Zajc, Barbara
, p. 3891 - 3893 (2011)
Modular synthesis of vinyl and fluorovinyl triazoles can be achieved from bifunctional propargyl and fluoropropargyl sulfones by Cu-catalyzed azide-alkyne ligation and Julia-Kocienski olefination. Competitive click reactions of the protio and fluoropropar
E- or Z-Selective synthesis of 4-fluorovinyl-1,2,3-triazoles with fluorinated second-generation Julia-Kocienski reagents
Kumar, Rakesh,Singh, Govindra,Todaro, Louis J.,Yang, Lijia,Zajc, Barbara
, p. 1536 - 1549 (2015/01/30)
A highly modular approach to N-substituted 4-(1-fluorovinyl)triazoles is described. In situ desilylation and Cu-catalyzed ligation reaction of TMS-protected α-fluoropropargyl benzothiazole sulfone with aryl, alkyl, and metallocenyl azides furnished second
