1299293-79-0

Basic information

• Product Name: (1R,2S)-1-[2-(benzyloxy)ethyl]-2-methylpent-4-en-1-yl (4S,5R)-5-{[tert-butyl(dimethyl)-silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate
• Synonyms: (1R,2S)-1-[2-(benzyloxy)ethyl]-2-methylpent-4-en-1-yl (4S,5R)-5-{[tert-butyl(dimethyl)-silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate
• CAS NO: 1299293-79-0
• Molecular Weight: 612.923
• Mol File: 1299293-79-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S)-1-[2-(benzyloxy)ethyl]-2-methylpent-4-en-1-yl (4S,5R)-5-{[tert-butyl(dimethyl)-silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-1-[2-(benzyloxy)ethyl]-2-methylpent-4-en-1-yl (4S,5R)-5-{[tert-butyl(dimethyl)-silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate(1299293-79-0)
• EPA Substance Registry System: (1R,2S)-1-[2-(benzyloxy)ethyl]-2-methylpent-4-en-1-yl (4S,5R)-5-{[tert-butyl(dimethyl)-silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate(1299293-79-0)

Safety Data

• Hazardous Substances Data: 1299293-79-0(Hazardous Substances Data)

Upstream product

• 743472-03-9 (4R)-4-benzyl-3-{(2R,3R)-3-hydroxy-4-[(4-methoxybenzyl)oxy]-2-methylbutanoyl}-1,3-oxazolidin-2-one 
• 501419-20-1 (2S,3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-4-[(4-methoxybenzyl)oxy]-2-methylbutan-1-ol 
• 501419-21-2 3R-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2R-methyl-butyraldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 100-39-0 benzyl bromide 
• 121289-23-4 p-methoxybenzyloxyacetaldehyde 
• 19790-60-4 3-Benzyloxypropanal 
• 109786-74-5 (±)-3-(4-methoxybenzyloxy)propane-1,2-diol 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 1299293-77-8 (4S,5R)-5-[2-(benzyloxy)ethyl]-4-methyltetrahydrofuran-2-ol 
• 1299293-76-7 (3R,4S)-1-(benzyloxy)-4-methylhex-5-yn-3-ol 
• 1299293-74-5 ethyl (4S,5R)-5-{[tert-butyl(dimethyl)silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate 
• 1299293-73-4 ethyl (2E,4S,5R)-5-{[tert-butyl(dimethyl)silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhex-2-enoate 
• 1299293-72-3 (4R)-4-benzyl-3-{(2R,3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-4-[(4-methoxybenzyl)oxy]-2-methylbutanoyl}-1,3-oxazolidin-2-one 

Downstream Products

• 1299293-80-3 (2R,3S)-2-(2-(benzyloxy)ethyl)-6-((3S,4R)-4-tert-butyldimethylsilyloxy-5-(4-methoxybenzyloxy)-3-methylpentyl)-3-methyl-3,4-dihydro-2H-pyran 
• 1299293-81-4 (2R,3S)-5-{(2R,3S)-2-[2-(benzyloxy)ethyl]-3-methyl-3,4-dihydro-2H-pyran-6-yl}-1-[(4-methoxybenzyl)oxy]-3-methylpentan-2-ol 

Relevant articles and documents

Synthesis of the spirofungin a core via a domino strategy consisting of olefinic ester ring-closing metathesis and iodospiroacetalization

Olefination of ester 26 which was obtained from acid 20 and alkenol 25 using a reduced titanium ethylidene reagent led to cyclic enol ether 28 which could be cyclized by iodospiroacetalization to the spiroacetal core of the antifungal compound spirofungin