3175-23-3

Usage

Safety Profile

Moderately toxic by ingestion. Ahuman eye irritant. When heated to decomposition itemits toxic fumes of Clí.

InChI:InChI=1/C3H5Cl3/c1-3(5,6)2-4/h2H2,1H3

Upstream product

• 557-98-2 2-chloropropene 
• 187737-37-7 propene 
• 26198-63-0 1,2-Dichloropropane 
• 110-22-5 diacetyl peroxide 
• 594-20-7 2,2-dichloropropane 
• 78-95-5 chloroacetone 
• 78-88-6 2,3-Dichloroprop-1-ene 
• 420-45-1 2,2-difluoropropane 
• 7782-50-5 chlorine 
• 7647-18-9 antimonypentachloride 
• 7446-70-0 aluminium trichloride 
• 7791-25-5 sulfuryl dichloride 
• 105-74-8 dilauryl peroxide 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 557-98-2 2-chloropropene 
• 7069-38-7 trans-1,3-dichloropropylene 
• 13116-53-5 1,2,2,3-tetrachloropropane 

Relevant academic research and scientific papers

SULFURYL CHLORIDE AS CHLORINATING AGENT

The use of sulfuryl chloride, either alone or in combination with chlorine, as a chlorinating agent is disclosed.

PROCESS FOR THE PRODUCTION OF CHLORINATED AND/OR BROMINATED PROPANES AND/OR PROPENES

Processes for the production of chlorinated and/or brominated propanes and/or propenes are provided. The present processes make use of a feedstream comprising 1,2-dichloropropane and at least one bromination step. Regioselectivities of at least 90% to desired dichlorobromopropanes are provided. The present processes may also include one or more halogen exchange and/or dehydrohalogenation steps that leverage the regioselectivities provided by the initial bromination step.

PROCESS FOR THE PRODUCTION OF CHLORINATED PROPENES

Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. The present processes can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings. Finally, the processes are advantageously conducted in the liquid phase, thereby presenting additional savings as compared to conventional, gas phase processes.

MANUFACTURE OF DICHLOROPROPANOL

Manufacture of dichloropropanol Process for manufacturing dichloropropa nol wherein a glycerol-based product comprising at least one diol containi ng at least 3 carbon atoms other than 1,2- propanediol, is reacted with a chlorinati ng agent, and of products derived from dichloropropanol such as ep ichlorohydrin and epoxy resins. No figure.

REACTION OF ALKANES, ETHERS AND ALIPHATIC KETONES WITH THE SF4-HF-Cl2 SYSTEM

The reaction of alkanes, ethers, and aliphatic ketones with the SF4-HF-Cl2 system takes place through formation of unsaturated compounds followed by addition of the chloride and fluoride ions.The presence of sulfur tetrafluoride in the rection mixture pro