1313757-66-2Relevant academic research and scientific papers
Synthesis and characterization of a ferrocene-linked bis-fullerene[60] dumbbell
Andersson, Claes-Henrik,Nyholm, Leif,Grennberg, Helena
, p. 2374 - 2381 (2012/03/22)
A new [60]fullerene dumbbell consisting of two fulleropyrrolidines connected to a central ferrocene unit by amide linkages has been prepared and fully characterized by elemental analysis, 1H NMR, UV/Vis, fluorescence and mass spectrometry. The electrochemical properties as determined by cyclic voltammetry show ground state electronic communication between the ferrocene and the fullerene units. In addition, the preparaton of a ferrocene building block for an alternative linking approach is presented. The Royal Society of Chemistry 2012.
A convenient synthesis of new chromophoric tetracyanobutadiene-scaffolded peptides via a dipolar [2+2] cycloaddition-cycloreversion reaction
Rijkers, Dirk T.S.,Diederich, Fran?ois
scheme or table, p. 4021 - 4025 (2011/08/21)
Herein, we report a novel approach for the synthesis of π-conjugated peptide-based donor-acceptor (D-π-A) chromophores, by reacting electron-rich alkynes with tetracyanoethylene. The desired tetracyanobutadiene-scaffolded peptides were obtained in good yields with various optical properties, λmax: 321-492 nm, ε: 21,000-65,000 mol-1 dm3 cm-1 depending on the substitution pattern of the cyanobutadiene scaffold.
